Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 14, Problem 6E
A
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Please help me figure out what the slope is and how to calculate the half life Using the data provided.
Curved arrows are used to illustrate the flow of electrons. Follow
the curved arrows and draw the structure of the missing
reactants, intermediates, or products in the following mechanism.
Include all lone pairs. Ignore stereochemistry. Ignore inorganic
byproducts.
H
Br2 (1 equiv)
H-
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Starting Alkene
Draw Major
Product
I
I
H2O
四:
⑦..
Q
Draw Major
Charged
Intermediate
I
NH (aq)+CNO (aq) → CO(NH2)2(s)
Experiment
[NH4] (M) [CNO] (M) Initial rate (M/s)
1
0.014
0.02
0.002
23
0.028
0.02
0.008
0.014
0.01
0.001
Calculate the rate contant for this reaction using the data provided in the table.
Chapter 14 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 14 - Prob. 1ECh. 14 - Which of the following gas samples would have the...Ch. 14 - Prob. 3ECh. 14 - Prob. 4ECh. 14 - Prob. 5ECh. 14 - A 0.512mol sample of argon gas is collected at a...Ch. 14 - Prob. 7ECh. 14 - Prob. 8ECh. 14 - At what temperature (C) will 0.810mol of chlorine...Ch. 14 - Prob. 10E
Ch. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - Prob. 17ECh. 14 - Prob. 18ECh. 14 - Prob. 19ECh. 14 - A sample of an unknown gas is found to have a...Ch. 14 - Prob. 21ECh. 14 - Prob. 22ECh. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Prob. 25ECh. 14 - Prob. 26ECh. 14 - Prob. 27ECh. 14 - The molar volume for oxygen gas at a pressure of...Ch. 14 - Prob. 29ECh. 14 - Prob. 30ECh. 14 - Prob. 31ECh. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Prob. 34ECh. 14 - Prob. 35ECh. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - Prob. 38ECh. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - Prob. 44ECh. 14 - Prob. 45ECh. 14 - Prob. 46ECh. 14 - Prob. 47ECh. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Prob. 50ECh. 14 - Prob. 51ECh. 14 - Prob. 52ECh. 14 - Prob. 53ECh. 14 - Prob. 54ECh. 14 - Prob. 55ECh. 14 - Prob. 56ECh. 14 - Prob. 57ECh. 14 - Prob. 14.1TCCh. 14 - Prob. 1PECh. 14 - Prob. 2PECh. 14 - Prob. 3PECh. 14 - Prob. 4PECh. 14 - Prob. 5PECh. 14 - Prob. 6PECh. 14 - Prob. 7PECh. 14 - Prob. 8PECh. 14 - Prob. 9PECh. 14 - Prob. 10PECh. 14 - Prob. 11PECh. 14 - Prob. 12PECh. 14 - Prob. 13PECh. 14 - Prob. 14PECh. 14 - Prob. 15PECh. 14 - Prob. 1CLECh. 14 - Prob. 2CLECh. 14 - Prob. 3CLECh. 14 - Prob. 4CLE
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- 2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.arrow_forward2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.arrow_forward1 2 3 4 I(aq) +OCl(aq) → IO¯¯(aq) + Cl¯(aq) Experiment [I-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 Calculate the overall order of this reaction using the table data. 0.0025 0.000069 0.0025 0.000140arrow_forward
- H2O2(aq) +3 I¯(aq) +2 H+(aq) → 13(aq) +2 H₂O(l)· ••• Experiment [H2 O2]o (M) [I]o (M) [H+]。 (M) Initial rate (M/s) 1 0.15 0.15 0.05 0.00012 234 0.15 0.3 0.05 0.00024 0.3 0.15 0.05 0.00024 0.15 0.15 0.1 0.00048 Calculate the overall order of this reaction using the table data.arrow_forwardThe U. S. Environmental Protection Agency (EPA) sets limits on healthful levels of air pollutants. The maximum level that the EPA considers safe for lead air pollution is 1.5 μg/m³ Part A If your lungs were filled with air containing this level of lead, how many lead atoms would be in your lungs? (Assume a total lung volume of 5.40 L.) ΜΕ ΑΣΦ = 2.35 1013 ? atoms ! Check your rounding. Your final answer should be rounded to 2 significant figures in the last step. No credit lost. Try again.arrow_forwardY= - 0.039 (14.01) + 0.7949arrow_forward
- Suppose 1.76 g of magnesium acetate (Mg (CH3CO2)2) are dissolved in 140. mL of water. Find the composition of the resulting electrolyte solution. In particular, list the chemical symbols (including any charge) of each dissolved ion in the table below. List only one ion per row. mEq Then, calculate the concentration of each ion in dwrite the concentration in the second column of each row. Be sure you round your answers to the L correct number of significant digits. ion Add Row mEq L x 5arrow_forwardA pdf file of your hand drawn, stepwise mechanisms for the reactions. For each reaction in the assignment, you must write each mechanism three times (there are 10 reactions, so 30 mechanisms). (A) do the work on a tablet and save as a pdf., it is expected to write each mechanism out and NOT copy and paste the mechanism after writing it just once. Everything should be drawn out stepwise and every bond that is formed and broken in the process of the reaction, and is expected to see all relevant lone pair electrons and curved arrows.arrow_forwardNonearrow_forward
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