Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 14, Problem 6E
A
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4.
a) Give a suitable rationale for the following cyclization, stating the type of process involved
(e.g. 9-endo-dig), clearly showing the mechanistic details at each step.
H
CO₂Me
1) NaOMe
2) H3O®
CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for
unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be
catalyzed the propylene molecules must first adsorb onto the surface. In order to completely
cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total
of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that
have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner
2. (a) Many main group oxides form acidic solutions when added to water. For example solid
tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced
chemical equation for this reaction.
(b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures
to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-)
and carbon monoxide. Write a balanced chemical equation for this reaction.
Chapter 14 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 14 - Prob. 1ECh. 14 - Which of the following gas samples would have the...Ch. 14 - Prob. 3ECh. 14 - Prob. 4ECh. 14 - Prob. 5ECh. 14 - A 0.512mol sample of argon gas is collected at a...Ch. 14 - Prob. 7ECh. 14 - Prob. 8ECh. 14 - At what temperature (C) will 0.810mol of chlorine...Ch. 14 - Prob. 10E
Ch. 14 - Prob. 11ECh. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - Prob. 17ECh. 14 - Prob. 18ECh. 14 - Prob. 19ECh. 14 - A sample of an unknown gas is found to have a...Ch. 14 - Prob. 21ECh. 14 - Prob. 22ECh. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Prob. 25ECh. 14 - Prob. 26ECh. 14 - Prob. 27ECh. 14 - The molar volume for oxygen gas at a pressure of...Ch. 14 - Prob. 29ECh. 14 - Prob. 30ECh. 14 - Prob. 31ECh. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Prob. 34ECh. 14 - Prob. 35ECh. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - Prob. 38ECh. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - Prob. 44ECh. 14 - Prob. 45ECh. 14 - Prob. 46ECh. 14 - Prob. 47ECh. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Prob. 50ECh. 14 - Prob. 51ECh. 14 - Prob. 52ECh. 14 - Prob. 53ECh. 14 - Prob. 54ECh. 14 - Prob. 55ECh. 14 - Prob. 56ECh. 14 - Prob. 57ECh. 14 - Prob. 14.1TCCh. 14 - Prob. 1PECh. 14 - Prob. 2PECh. 14 - Prob. 3PECh. 14 - Prob. 4PECh. 14 - Prob. 5PECh. 14 - Prob. 6PECh. 14 - Prob. 7PECh. 14 - Prob. 8PECh. 14 - Prob. 9PECh. 14 - Prob. 10PECh. 14 - Prob. 11PECh. 14 - Prob. 12PECh. 14 - Prob. 13PECh. 14 - Prob. 14PECh. 14 - Prob. 15PECh. 14 - Prob. 1CLECh. 14 - Prob. 2CLECh. 14 - Prob. 3CLECh. 14 - Prob. 4CLE
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