Concept explainers
Interpretation: The titration curve for strong acid and strong base; The major species present before and after the reaction at various points in the curve; reaction that takes place in a strong
Concept introduction: The strong acid has a tendency to undergo complete dissociation. In the same way a strong base is the one that undergoes complete dissociation in aqueous solution.
To determine: The titration curve for strong acid and strong base; The major species present before and after the reaction at various points in the curve; reaction that takes place in a strong acid-strong base titration,
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Chapter 14 Solutions
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- Consider the nanoscale-level representations for Question 110 of the titration of the aqueous weak acid HX with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: After a very small volume of titrant has been added to the initial HX solution? When enough titrant has been added to take the solution just past the equivalence point? Halfway to the equivalence point? At the equivalence point? Nanoscale representations for Question 110.arrow_forwardThe titration curves for two acids with the same base are shown on this graph. (a) Which is the curve for the weaker acid? Explain your choice. (b) Give the approximate pH at the equivalence point for the titration of each acid. (c) Explain why the pH at the equivalence point differs for each acid. (d) Explain why the starting pH values of the two acids differ. (e) Which indicator or indicators, phenolphthalein, bromthymol blue, or methyl red, could be used for the titration of Acid 1? For the titration of Acid 2? Explain your choices.arrow_forwardBriefly describe how a buffer solution can control the pH of a solution when strong acid is added and when strong base is added. Use NH3/NH4Cl as an example of a buffer and HCl and NaOH as the strong acid and strong base.arrow_forward
- Explain why even though an aqueous acetic acid solution contains acetic acid and acetate ions, it cannot be a buffer.arrow_forwardWhat is the pH of a buffer that is 0.150 M in a weak acid and 0.150 M in the acids conjugate base? The acids ionization constant is 6.8 106.arrow_forwardConsider the nanoscale-level representations for Question 111 of the titration of the aqueous strong acid HA with aqueous NaOH, the titrant. Water molecules and Na+ ions are omitted for clarity. Which diagram corresponds to the situation: (a) After a very small volume of titrant has been added to the initial HA solution? (b) Halfway to the equivalence point? (c) When enough titrant has been added to take the solution just past the equivalence point? (d) At the equivalence point? Nanoscale representations for Question 111.arrow_forward
- The three flasks shown below depict the titration of an aqueous NaOH solution with HCl at different points. One represents the titration prior to the equivalence point, another represents the titration at the equivalence point, and the other represents the titration past the equivalence point. (Sodium ions and solvent water molecules have been omitted for clarity.) a Write the balanced chemical equation for the titration. b Label each of the beakers shown to indicate which point in the titration they represent. c For each solution, indicate whether you expect it to be acidic, basic, or neutral.arrow_forwardThe titration of 0.100 M acetic acid with 0.100 M NaOH is described in the text. What is the pH of the solution when 35.0 mL of the base has been added to 100.0 mL of 0.100 M acetic acid?arrow_forwardAnother way to treat data from a pH titration is to graph the absolute value of the change in pH per change in milliliters added versus milliliters added (pH/mL versus mL added). Make this graph using your results from Exercise 61. What advantage might this method have over the traditional method for treating titration data?arrow_forward
- A solution of weak base is titrated to the equivalence point with a strong acid. Which one of the following statements is most likely to be correct? a The pH of the solution at the equivalence point is 7.0. b The pH of the solution is greater than 13.0. c The pH of the solution is less than 2.0. d The pH of the solution is between 2.0 and 7.0. e The pH of the solution is between 7.0 and 13.0. The reason that best supports my choosing the answer above is a Whenever a solution is titrated with a strong acid, the solution will be very acidic. b Because the solution contains a weak base and the acid (titrant) is used up at the equivalence point, the solution will be basic. c Because the solution contains the conjugate acid of the weak base at the equivalence point, the solution will be acidic.arrow_forwardWhat is meant by the capacity of a buffer? Describe a buffer with low capacity and the same buffer with greater capacity.arrow_forwardIdentify each pair that could form a buffer. (a) NaOH and NaCl (b) NaOH and NH3 (c) Na3PO4 and Na2HPO4arrow_forward
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