PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
expand_more
expand_more
format_list_bulleted
Question
Chapter 14, Problem 14.93E
Interpretation Introduction
Interpretation:
The way by which the two Raman spectra are different is to be stated. The way by which the two Raman spectra are same is to be stated
Concept introduction:
The spectroscopy that is used to study the vibrational, rotational and another various low frequency modes inside the system is known as Raman spectroscopy. Raman spectroscopy is used to give the fingerprint of the structure for their identification.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Is the bond length in 1HCl the same as that in 2HCl? The wavenumbers of the J = 1 ← 0 rotational transitions for 1H35Cl and 2H35Cl are 20.8784 and 10.7840 cm–1, respectively. Accurate atomic masses are 1.007 825mu and 2.0140mu for 1H and 2H, respectively. The mass of 35Cl is 34.968 85mu. Based on this information alone, can you conclude that the bond lengths are the same or different in the two molecules?
Study the IR and Raman activity of C-O
stretches in fac-FeCl3(CO)3
Identify the IR and Raman bands.
A molecule absorbs radiation of frequency 3.00x1014 Hz. What is the energy difference between the molecular energy states involved?
Chapter 14 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 14 - Prob. 14.1ECh. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8ECh. 14 - Prob. 14.9ECh. 14 - Prob. 14.10E
Ch. 14 - Prob. 14.11ECh. 14 - Prob. 14.12ECh. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Diatomic sulfur, S2, was detected in the tail of...Ch. 14 - Prob. 14.16ECh. 14 - Prob. 14.17ECh. 14 - Prob. 14.18ECh. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Which of the following molecules should have pure...Ch. 14 - Which of the following molecules should have pure...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - Derive equation 14.21 from the E expression...Ch. 14 - Prob. 14.28ECh. 14 - Prob. 14.29ECh. 14 - Lithium hydride, 7Li1H, is a potential fuel for...Ch. 14 - Prob. 14.31ECh. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Prob. 14.36ECh. 14 - From the data in Table 14.2, predict B for DCl D...Ch. 14 - A colleague states that the pure rotational...Ch. 14 - Prob. 14.39ECh. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Prob. 14.42ECh. 14 - Prob. 14.43ECh. 14 - Determine E for J=20J=21 for HBr assuming it acts...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Prob. 14.47ECh. 14 - Prob. 14.48ECh. 14 - Prob. 14.49ECh. 14 - Prob. 14.50ECh. 14 - Prob. 14.51ECh. 14 - Prob. 14.52ECh. 14 - Prob. 14.53ECh. 14 - Prob. 14.54ECh. 14 - Prob. 14.55ECh. 14 - Prob. 14.56ECh. 14 - Prob. 14.57ECh. 14 - Prob. 14.58ECh. 14 - Prob. 14.59ECh. 14 - Prob. 14.60ECh. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Prob. 14.63ECh. 14 - Prob. 14.64ECh. 14 - Prob. 14.65ECh. 14 - Prob. 14.66ECh. 14 - Prob. 14.68ECh. 14 - Prob. 14.69ECh. 14 - Prob. 14.70ECh. 14 - Prob. 14.71ECh. 14 - Prob. 14.72ECh. 14 - Prob. 14.73ECh. 14 - Prob. 14.74ECh. 14 - Prob. 14.75ECh. 14 - Prob. 14.76ECh. 14 - Prob. 14.77ECh. 14 - Prob. 14.78ECh. 14 - Prob. 14.79ECh. 14 - Prob. 14.80ECh. 14 - Prob. 14.81ECh. 14 - Prob. 14.82ECh. 14 - Prob. 14.83ECh. 14 - Prob. 14.84ECh. 14 - Prob. 14.85ECh. 14 - Dioctyl sulfide, (C8H17)2S, and hexadecane,...Ch. 14 - Where would you expect vibrations for ethyl...Ch. 14 - Prob. 14.88ECh. 14 - Prob. 14.89ECh. 14 - Prob. 14.90ECh. 14 - Prob. 14.91ECh. 14 - Prob. 14.92ECh. 14 - Prob. 14.93ECh. 14 - Prob. 14.94ECh. 14 - The mutual exclusion rule states that for certain...Ch. 14 - Prob. 14.96ECh. 14 - Prob. 14.97ECh. 14 - Prob. 14.98ECh. 14 - Prob. 14.99ECh. 14 - Construct and compare the energy level diagrams...Ch. 14 - Prob. 14.101E
Knowledge Booster
Similar questions
- Would the light from fireflies be considered an example of a fluorescence or a phosphorescence process?arrow_forward3 Calculate the frequencies and wavelengths for the rotational transition J = 0 → J = 1 and J = 4 → J = 5 for the HCl molecule. The internuclear distance is Re = 0.12745 nm. What is the frequency shift between the two isotopomers H35Cl and H37Cl for the two transitions?arrow_forwardFood dye spectroscopy 2. At what wavelengths should the readings be taken? What instrumentation will you utilize with a solution of a known dye to determine the wavelength for your analysis?arrow_forward
- How would a decrease in the wavelength of light affect the resolution power of a bright-field microscope?arrow_forwardBy how many joules is the energy of a molecule increased when it absorbs (a) visible light with a wavelength of 500 nm or (b) infrared radiation with a wavenumber of 1 251 cm-1?arrow_forwardWhat is the difference between an absorption spectrum and a standard curve?arrow_forward
- 5. Atomic emission spectroscopy relies on emission of light by the analyte. An ICP plasma has a temperature of 6200 K for a particular instrument. Using the Boltzmann equation, describe the relative intensities for a signal with a wavelength of 300 nm versus a signal with a wavelength of 600 nm.arrow_forwardSpectroscopy relies on the excitation and relaxation of electrons. Which of the following statements about spectroscopy is true? Phosphorescence is the emission of a photon of light as an electron transitions from the excited singlet state to ground state. Collisional deactivation of an excited molecule decreases the absorbance response. Molecular absorption spectrometry measures the change in light intensity as light passes through a sample. Fluorescence is the absorption of a photon of light as an electron transitions from the ground state to an excited triplet state.arrow_forward10. The Raman spectroscopy instrument records data and then plots signal intensity vs. raman shift. What are the actual wavelengths that are (1) emitted by the laser within the instrument that is directed at the sample and (2) that are sent back to the instrument due to a Raman interaction with your sample of dry ice that has a Raman active IR band at 1300 cm³¹.arrow_forward
- Hooke's Law and Spectroscopyarrow_forwardThe rotational spectrum of CH* has been observed in the planetary nebula NGC 7027." The spectrum shows a series of lines separated by 29.64 cm1. Calculate the bond length of CH*. Take the reduced mass of CH* to be 0.9299 g/mol. Give your answer in angstroms with two decimal places. Answer:arrow_forwardThe “signature” infrared absorption that indicates the presence of a C-H stretching motion in a molecule occurs at wavelengths near 3.4 × 10-6m. Use this information to estimate the force constant of the C-H stretch.Take the reduced mass in this motion to be approximately equal to the mass of the hydrogen atom (a good approximation when the H atom is attached to a heavy atom).arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning