Chemistry
13th Edition
ISBN: 9781260162370
Author: Chang
Publisher: MCG
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Textbook Question
Chapter 14, Problem 14.71QP
Consider the following reacting system:
What combination of temperature and pressure (high or low) would maximize the yield of nitrosyl chloride (NOCl)? [Hint: You will also need to consult Appendix 2.]
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Students have asked these similar questions
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following
compounds. Please show your work. (8) SF2, CH,OH, C₂H₂
b) Based on your answers given above, list the compounds in order of their Boiling Point
from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road-
maps to see how the combined reactions allow you to "navigate" between the different
functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18
roadmaps along with your new Chapter 19 roadmap for these.
(a)
1. BHS
2. H₂O₂
3. H₂CrO4
4. SOCI₂
(b)
1. Cl₂/hv
2. KOLBU
3. H₂O, catalytic H₂SO4
4. H₂CrO4
Reaction
Roadmap
An alkene 5. EtOH
6.0.5 Equiv. NaOEt/EtOH
7. Mild H₂O
An alkane
1.0
2. (CH3)₂S
3. H₂CrO
(d)
(c)
4. Excess EtOH, catalytic H₂SO
OH
4. Mild H₂O*
5.0.5 Equiv. NaOEt/EtOH
An alkene 6. Mild H₂O*
A carboxylic
acid
7. Mild H₂O*
1. SOC₁₂
2. EtOH
3.0.5 Equiv. NaOEt/E:OH
5.1.0 Equiv. NaOEt
6.
NH₂
(e)
1. 0.5 Equiv. NaOEt/EtOH
2. Mild H₂O*
Br
(f)
i
H
An aldehyde
1. Catalytic NaOE/EtOH
2. H₂O*, heat
3. (CH,CH₂)₂Culi
4. Mild H₂O*
5.1.0 Equiv. LDA
Br
An ester
4. NaOH, H₂O
5. Mild H₂O*
6. Heat
7.
MgBr
8. Mild H₂O*
7. Mild H₂O+
Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water?
Group of answer choices
LiBr
LiI
LiF
LiCl
Chapter 14 Solutions
Chemistry
Ch. 14.1 - Consider the equilibrium XY, where the forward...Ch. 14.1 - The equilibrium constant Kc for a particular...Ch. 14.2 - Write Kc and Kp for the decomposition of...Ch. 14.2 - Carbonyl chloride (COCl2), also called phosgene,...Ch. 14.2 - Prob. 4PECh. 14.2 - Write equilibrium constant expressions for Kc and...Ch. 14.2 - Consider the following equilibrium at 395 K:...Ch. 14.2 - Prob. 7PECh. 14.2 - For which of the following reactions is Kc equal...Ch. 14.2 - You are given the equilibrium constant for the...
Ch. 14.2 - From the following equilibrium constant...Ch. 14.2 - Write the equilibrium constant expression for the...Ch. 14.3 - The equilibrium constant (Kc) for reaction AB+C is...Ch. 14.4 - The equilibrium constant (Kc) for the formation of...Ch. 14.4 - Consider the reaction in Example 14.9. Starting...Ch. 14.4 - At 1280C the equilibrium constant (Kc) for the...Ch. 14.4 - Use the following information to answer questions...Ch. 14.4 - Use the following information to answer questions...Ch. 14.4 - The equilibrium constant (Kc) for the A2+B22AB...Ch. 14.5 - At 430C, the equilibrium constant (KP) for the...Ch. 14.5 - Consider the equilibrium reaction involving...Ch. 14.5 - Consider the equilibrium between molecular oxygen...Ch. 14.5 - Prob. 1RCFCh. 14.5 - The diagram here shows the gaseous reaction 2AA2...Ch. 14.5 - The diagrams shown here represent the reaction...Ch. 14 - Define equilibrium. Give two examples of a dynamic...Ch. 14 - Explain the difference between physical...Ch. 14 - What is the law of mass action?Ch. 14 - Briefly describe the importance of equilibrium in...Ch. 14 - Define homogeneous equilibrium and heterogeneous...Ch. 14 - Prob. 14.6QPCh. 14 - Write the expressions for the equilibrium...Ch. 14 - Write equilibrium constant expressions for Kc, and...Ch. 14 - Write the equilibrium constant expressions for Kc...Ch. 14 - Write the equation relating Kc to KP, and define...Ch. 14 - What is the rule for writing the equilibrium...Ch. 14 - Give an example of a multiple equilibria reaction.Ch. 14 - Problems 14.13The equilibrium constant for the...Ch. 14 - The following diagrams represent the equilibrium...Ch. 14 - The equilibrium constant (Kc) for the reaction...Ch. 14 - Consider the following equilibrium process at...Ch. 14 - What is KP at 1273C for the reaction...Ch. 14 - The equilibrium constant KP for the reaction...Ch. 14 - Consider the following reaction: N2(g)+O2(g)2NO(g)...Ch. 14 - A reaction vessel contains NH3, N2, and H2 at...Ch. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - At equilibrium, the pressure of the reacting...Ch. 14 - The equilibrium constant KP for the reaction...Ch. 14 - Ammonium carbamate, NH4CO2NH2, decomposes as...Ch. 14 - Consider the following reaction at 1600C....Ch. 14 - Pure phosgene gas (COCl2), 3.00 102 mol, was...Ch. 14 - Consider the equilibrium 2NOBr(g)2NO(g)+Br2(g) If...Ch. 14 - A 2.50-mole quantity of NOCl was initially in a...Ch. 14 - The following equilibrium constants have been...Ch. 14 - The following equilibrium constants have been...Ch. 14 - The following equilibrium constants were...Ch. 14 - At a certain temperature the following reactions...Ch. 14 - Based on rate constant considerations, explain why...Ch. 14 - Explain why reactions with large equilibrium...Ch. 14 - Water is a very weak electrolyte that undergoes...Ch. 14 - Consider the following reaction, which takes place...Ch. 14 - Define reaction quotient. How does it differ from...Ch. 14 - Prob. 14.38QPCh. 14 - The equilibrium constant KP for the reaction...Ch. 14 - For the synthesis of ammonia N2(g)+2H2(g)2NH3(g)...Ch. 14 - For the reaction H2(g)+CO2(g)H2O(g)+CO(g) at 700C,...Ch. 14 - At 1000 K, a sample of pure NO2 gas decomposes:...Ch. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - The dissociation of molecular iodine into iodine...Ch. 14 - The equilibrium constant Kc for the decomposition...Ch. 14 - Consider the following equilibrium process at...Ch. 14 - Consider the heterogeneous equilibrium process:...Ch. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - Explain Le Chteliers principle. How can this...Ch. 14 - Use Le Chteliers principle to explain why the...Ch. 14 - List four factors that can shift the position of...Ch. 14 - Does the addition of a catalyst have any effects...Ch. 14 - Consider the following equilibrium system...Ch. 14 - Heating solid sodium bicarbonate in a closed...Ch. 14 - Consider the following equilibrium systems: (a)...Ch. 14 - Consider the equilibrium 2I(g)2I2(g) What would be...Ch. 14 - Consider the following equilibrium process:...Ch. 14 - Consider the reaction...Ch. 14 - In the uncatalyzed reaction N2O4(g)2NO2(g) the...Ch. 14 - Consider the gas-phase reaction...Ch. 14 - Consider the statement: The equilibrium constant...Ch. 14 - Pure nitrosyl chloride (NOCl) gas was heated to...Ch. 14 - Determine the initial and equilibrium...Ch. 14 - Diagram (a) shows the reaction A2(g)+B2(g)2AB(g)...Ch. 14 - The equilibrium constant (KP) for the formation of...Ch. 14 - Baking soda (sodium bicarbonate) undergoes thermal...Ch. 14 - Consider the following reaction at equilibrium:...Ch. 14 - The equilibrium constant KP for the reaction...Ch. 14 - Consider the following reacting system:...Ch. 14 - At a certain temperature and a total pressure of...Ch. 14 - Consider the reaction 2NO(g)+O2(g)2NO2(g) At 430C,...Ch. 14 - When heated, ammonium carbamate decomposes as...Ch. 14 - A mixture of 0.47 mole of H2 and 3.59 moles of HCl...Ch. 14 - When heated at high temperatures, iodine vapor...Ch. 14 - One mole of N2 and three moles of H2 are placed in...Ch. 14 - Prob. 14.79QPCh. 14 - A quantity of 6.75 g of SO2Cl2 was placed in a...Ch. 14 - Prob. 14.81QPCh. 14 - Prob. 14.82QPCh. 14 - Eggshells are composed mostly of calcium carbonate...Ch. 14 - The equilibrium constant KP for the following...Ch. 14 - When dissolved in water, glucose (corn sugar) and...Ch. 14 - At room temperature, solid iodine is in...Ch. 14 - Prob. 14.89QPCh. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - When heated, a gaseous compound A dissociates as...Ch. 14 - When a gas was heated under atmospheric...Ch. 14 - Prob. 14.93QPCh. 14 - At 20C, the vapor pressure of water is 0.0231 atm....Ch. 14 - Industrially, sodium metal is obtained by...Ch. 14 - In the gas phase, nitrogen dioxide is actually a...Ch. 14 - Prob. 14.99QPCh. 14 - The equilibrium constant for the reaction 4X+Y3Z...Ch. 14 - About 75 percent of hydrogen for industrial use is...Ch. 14 - Prob. 14.102QPCh. 14 - Consider the decomposition of ammonium chloride at...Ch. 14 - At 25C, the equilibrium partial pressures of NO2...Ch. 14 - Prob. 14.105QPCh. 14 - Prob. 14.107QPCh. 14 - Prob. 14.108QPCh. 14 - At 25C, a mixture of NO2 and N2O4 gases are in...Ch. 14 - A student placed a few ice cubes in a drinking...Ch. 14 - Consider the potential energy diagrams for two...Ch. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - Prob. 14.113QPCh. 14 - The equilibrium constant (KP) for the reaction...Ch. 14 - The forward and reverse rate constants for the...Ch. 14 - Consider the reaction between NO2 and N2O4 in a...Ch. 14 - Prob. 14.118QPCh. 14 - (a) Use the vant Hoff equation in Problem 14.118...Ch. 14 - The KP for the reaction SO2Cl2(g)SO2(g)+Cl2(g) is...Ch. 14 - Prob. 14.121QPCh. 14 - Consider the following equilibrium system:...Ch. 14 - Prob. 14.125QPCh. 14 - Estimate the vapor pressure of water at 60C (see...
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