The number of ether groups in the given molecule. Interpretation: The number of ether groups in the given molecule is to be identified. Concept introduction: The ether group is represented by R − O − R . Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

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Answer 1

Question

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

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1. This experiment is more about understanding the colligative properties of a solution rather than the determination of the molar mass of a solid. a. Define colligative properties. b. Which of the following solutes has the greatest effect on the colligative properties for a given mass of pure water? Explain. (i) 0.01 mol of CaCl2 (ii) 0.01 mol of KNO3 (iii) 0.01 mol of CO(NH2)2 (an electrolyte) (an electrolyte) (a nonelectrolyte)

5. b. For Trials 2 and 3, the molar mass of the solute was 151 g/mol and 143 g/mol respectively. a. What is the average molar mass of the solute ? b. What are the standard deviation and the relative standard deviation (%RSD) for the molar mass of the solute ?

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Answer 2

Question

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

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Answer 3

Question

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

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Answer 4

Question

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

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Answer 5

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

Answer 6

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

Answer 7

Chapter 14, Problem 14.54SP

(a)

Interpretation Introduction

To determine: The number of ether groups in the given molecule.

Interpretation: The number of ether groups in the given molecule is to be identified.

Concept introduction: The ether group is represented by R−O−R. Ethers are of two types. If the alkyl groups attached on either sides of the oxygen atom are the same then the ethers are known as symmetrical ethers. If the alkyl groups attached on either sides of the oxygen atom are different then the ether is known as asymmetrical ether.

Answer 8

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

Answer 9

(b)

Interpretation Introduction

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

Answer 10

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

Answer 11

(c)

Interpretation Introduction

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

Answer 12

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

Answer 13

(d)

Interpretation Introduction

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

Answer 14

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

Answer 15

(e)

Interpretation Introduction

To determine: The number of stereoisomers in the given molecule.

Interpretation: The number of stereoisomers in the given molecule is to be calculated.

Concept introduction: The isomeric molecules having same molecular formula but different special arrangement of their atoms in space are called stereoisomer.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2P Ch. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5P Ch. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8P Ch. 14.5 - Prob. 14.9P Ch. 14.6 - Prob. 14.10P

Solution Summary: The author explains the number of ether groups in the given molecule.

Concept explainers

To determine: The other oxygen-containing functional group in the given compound.

Interpretation: The other oxygen-containing functional group in the given compound is to be identified.

Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

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Chapter 14 Solutions

Solution Summary: The author explains the number of ether groups in the given molecule.

Concept explainers

To determine: The other oxygen-containing functional group in the given compound. Interpretation: The other oxygen-containing functional group in the given compound is to be identified. Concept introduction: The alcohol group is represented by R−O−H and the ester group is represented as RCOOR.

To determine: The number of atoms present in the large ring. Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified. Concept introduction: Large ring contains large number of atoms called macrolide.

To determine: The number of chiral centres in the given molecule. Interpretation: The number of chiral centres in the given molecule is to be identified. Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.

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Chapter 14 Solutions

To determine: The number of atoms present in the large ring.

Interpretation: Large ring contains large number of atoms called macrolide. The number of atoms present in the large ring is to be identified.

Concept introduction: Large ring contains large number of atoms called macrolide.

To determine: The number of chiral centres in the given molecule.

Interpretation: The number of chiral centres in the given molecule is to be identified.

Concept introduction: The substances that have four different groups and have non super imposable mirror image are chiral centers.