Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
9th Edition
ISBN: 9781292151229
Author: Wade, LeRoy G.
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 14, Problem 14.55SP
In 2012, a group led by Professor Masayuki Satake of the University of Tokyo reported the isolation and structure determination of a toxin from a marine algal bloom that decimated the fish population off the New Zealand coast in 1998. Extensive mass spectrometry and NMR experiments ultimately led to the structure shown below, named Brevisulcenal-F. (See Journal of the American Chemical Society, 2012, 134, 4963-4968.) This structure holds the record for the largest number of fused rings, at 17.
- a. How many other groups are present?
- b. How many alcohol groups are present? Classify the alcohols as 1° or 2° or 3°.
- c. Are there any other oxygen-containing
functional groups ? Which, if any?
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Don't used hand raiting and don't used Ai solution
Explain the term “inductively coupled plasma.”
Using Pauling electronegativity values and a Ketelaar triangle, what type of compound is brass, a CuZn alloy?
Group of answer choices
metallic
ionic
covalent
Chapter 14 Solutions
Organic Chemistry Plus Masteringchemistry With Pearson Etext, Global Edition
Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2PCh. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5PCh. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8PCh. 14.5 - Prob. 14.9PCh. 14.6 - Prob. 14.10P
Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Challenging samples: 1. Metal complexes with low volatility are often difficult to analyze when performing atomic absorption measurements because the atomization efficiency is reduced to unacceptably low levels. Devise a strategy or strategies for eliminating the problem of a non-volatile metal complex? Explain how you would do that. 2. Devise a strategy to overcome unwanted ionization of the analyte? Explain what it would be. 3. Devise a general method that can be used to account for the presence of unknown matrix effects.arrow_forwardDon't used hand raitingarrow_forwardDon't used hand raiting don't used Ai solutionarrow_forward
- Homework: Atomic Structure This homework is due at the beginning of class next lecture period and is worth 6 points. Please place the number of protons and neutrons in the nucleus and then put the number of electrons in the correct shell. Also give the correct atomic mass. Also, state if the atom is an ion (cation or anion). H* 1. Number of protons Number of electrons Number of neutrons Atomic mass 2. 26 13AI +++ Number of protons Number of neutrons Number of electrons Atomic massarrow_forwardDon't used hand raitingarrow_forwardI need help working this problem out step by step, I was trying to use my example from the txt book but all I know how to do is set it up. I need to be shown step by step as I am a visual learner. Please help me.arrow_forward
- Don't used hand raitingarrow_forwardDon't used Ai solution and don't used hand raitingarrow_forward& Calculate the molar enthalpy of combustion (A combH) of 1.80 g of pyruvic acid (CH3COCOOH; 88.1 g mol-1) at 37 °C when they are combusted in a calorimeter at constant volume with a calorimeter constant = 1.62 kJ °C-1 and the temperature rose by 1.55 °C. Given: R = 8.314 J mol −1 °C-1 and the combustion reaction: AN C3H4O3 + 2.502(g) → 3CO2(g) + 2H2O(l)arrow_forward
- An unknown salt, AB, has the following precipitation reaction:A+(aq) + B-(aq) ⇌ AB(s) the K value for this reaction is 4.50 x10-6. Draw a model that represents what will happen when 1.00 L each of 1.00 M solution of A+(aq) and 1.00M solution of B-(aq) are combined.arrow_forward5. a) Use the rules in Example 4.4 (p. 99) and calculate sizes of octahedral and tetrahedral cavities in titanium and in zirconium. Use values for atomic radii given in Fig. 9.1 (p.291). (3 points) b) Consider the formation of carbides (MC) of these metals. Which metal is able to accommodate carbon atoms better, and which cavities (octahedral or tetrahedral) would be better suited to accommodate C atoms into metal's lattice? (4 points)arrow_forward2. Read paragraph 3.4 in your textbook ("Chiral Molecules"), and explain if Cobalt(ethylenediamine) 33+ shown in previous problem is a chiral species. If yes, draw projections of both enantiomers as mirror images, analogous to mirror projections of hands (below). Mirror (4 points)arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Characteristic Reactions of Benzene and Phenols; Author: Linda Hanson;https://www.youtube.com/watch?v=tjEqEjDd87E;License: Standard YouTube License, CC-BY
An Overview of Aldehydes and Ketones: Crash Course Organic Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=-fBPX-4kFlw;License: Standard Youtube License