Solution Manual for Quantitative Chemical Analysis
9th Edition
ISBN: 9781464175633
Author: Daniel Harris
Publisher: Palgrave Macmillan Higher Ed
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Question
Chapter 14, Problem 14.31P
Interpretation Introduction
Interpretation:
The net cell reaction and its equilibrium constant has to be calculated.
Concept introduction:
Nernst equation can be used to determine the cell potential at any instant, the difference from the standard state.
E = Eo - 0.05916 nlog [B]b[H+]m[A]a
Where:
E = cell potential under nonstandard conditions
E o = cell potential under standard conditions
n = number of moles of electrons exchanged in the
Finding K from Eo
K = 10nEo0.05916 at 25oC
Where K is equilibrium constant
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Post Lab Questions.
1) Draw the mechanism of your Diels-Alder cycloaddition.
2) Only one isomer of product is formed in the Diels-Alder cycloaddition. Why?
3) Imagine that you used isoprene as diene - in that case you don't have to worry about assigning endo
vs exo. Draw the "endo" and "exo" products of the Diels-Alder reaction between isoprene and maleic
anhydride, and explain why the distinction is irrelevant here.
4) This does not hold for other dienes. Draw the exo and endo products of the reaction of cyclohexadiene
with maleic anhydride. Make sure you label your answers properly as endo or exo.
100 °C
Xylenes
???
5) Calculate the process mass intensity for your specific reaction (make sure to use your actual amounts
of reagent).
Indicate the product(s) A, B C and D that are formed in
the reaction:
H
+ NH-NH-CH
[A+B]
[C+D]
hydrazones
How can you prepare a 6 mL solution of 6% H2O2, if we have a bottle of 30% H2O2?
Chapter 14 Solutions
Solution Manual for Quantitative Chemical Analysis
Ch. 14.1 - Prob. 1TYCh. 14.1 - Prob. 2TYCh. 14.1 - Prob. 3TYCh. 14.1 - Prob. 4TYCh. 14.2 - Prob. 5TYCh. 14.4 - Prob. 6TYCh. 14.4 - Prob. 7TYCh. 14.4 - Prob. 8TYCh. 14.5 - Prob. 9TYCh. 14.5 - Prob. 10TY
Ch. 14.6 - Prob. 11TYCh. 14.7 - Prob. 12TYCh. 14 - Prob. 14.AECh. 14 - Prob. 14.BECh. 14 - Prob. 14.CECh. 14 - Prob. 14.DECh. 14 - Prob. 14.EECh. 14 - Prob. 14.FECh. 14 - Prob. 14.GECh. 14 - Prob. 14.HECh. 14 - Prob. 14.IECh. 14 - Prob. 14.JECh. 14 - Prob. 14.KECh. 14 - Prob. 14.1PCh. 14 - Prob. 14.2PCh. 14 - Prob. 14.3PCh. 14 - Prob. 14.4PCh. 14 - Prob. 14.5PCh. 14 - Prob. 14.6PCh. 14 - Prob. 14.7PCh. 14 - Prob. 14.8PCh. 14 - Prob. 14.9PCh. 14 - Prob. 14.10PCh. 14 - Prob. 14.12PCh. 14 - Prob. 14.13PCh. 14 - Prob. 14.14PCh. 14 - Prob. 14.15PCh. 14 - Prob. 14.16PCh. 14 - Prob. 14.17PCh. 14 - Prob. 14.18PCh. 14 - Prob. 14.20PCh. 14 - Prob. 14.21PCh. 14 - Prob. 14.22PCh. 14 - Prob. 14.23PCh. 14 - Prob. 14.24PCh. 14 - Prob. 14.25PCh. 14 - Prob. 14.26PCh. 14 - Prob. 14.27PCh. 14 - Prob. 14.28PCh. 14 - Prob. 14.29PCh. 14 - Prob. 14.30PCh. 14 - Prob. 14.31PCh. 14 - Prob. 14.32PCh. 14 - Prob. 14.33PCh. 14 - Prob. 14.35PCh. 14 - Prob. 14.36PCh. 14 - Prob. 14.37PCh. 14 - Prob. 14.38PCh. 14 - Prob. 14.39PCh. 14 - Prob. 14.40PCh. 14 - Prob. 14.41PCh. 14 - Prob. 14.42PCh. 14 - Prob. 14.43PCh. 14 - Prob. 14.44PCh. 14 - Prob. 14.45PCh. 14 - Prob. 14.46PCh. 14 - Prob. 14.47PCh. 14 - Prob. 14.48PCh. 14 - Prob. 14.49PCh. 14 - Prob. 14.50PCh. 14 - Prob. 14.51PCh. 14 - Prob. 14.52PCh. 14 - Prob. 14.53P
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