(a) Interpretation: The correct name for 2-hexyn-4-ol is to be stated. Concept introduction: The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name. Rules for writing IUPAC name from the structural formula are given below. • First, identify the longest carbon chain. • The next step is to identify the groups attached to the longest chain. • Identify the position, location, and a number of the substituents bonded to the carbon chain. • Use prefix di, tri, tetra if the same type of substituents are present. • Name the substituents in alphabetical order.

Question

(4 pts - 2 pts each part) A route that can be taken to prepare a hydrophobic (water-repellent) aerogel is to start with trichloromethylsilane, CH3SiCl3 as the silicon source. a. What is the chemical reaction that this undergoes to form a product with Si-OH groups? Write as complete of a chemical equation as you can. CI CI-SI-CH3 CI b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you didn't already answer it in part (a)) and how/why does it form?

Answer 1

Question

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

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(4 pts - 2 pts each part) A route that can be taken to prepare a hydrophobic (water-repellent) aerogel is to start with trichloromethylsilane, CH3SiCl3 as the silicon source. a. What is the chemical reaction that this undergoes to form a product with Si-OH groups? Write as complete of a chemical equation as you can. CI CI-SI-CH3 CI b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you didn't already answer it in part (a)) and how/why does it form?

b) Circle the substrate that would not efficiently generate a Grignard reagent upon reaction with Mg in ether. CI Br ד c) Circle the Grignard reagents that contain incompatible functional groups. MgBr HO MgBr MgBr MgBr MgBr HO MgBr

Q2: Predict all organic product(s), including stereoisomers when applicable. PCC OH a) CH2Cl2 Page 2 of 5 Chem 0310 Organic Chemistry 1 HW Problem Sets b) .OH Na2Cr2O7, H+ OH PCC CH2Cl2 c) OH

Answer 2

Question

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

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Answer 3

Question

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

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Answer 4

Question

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

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Answer 5

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 6

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 7

Chapter 14, Problem 14.28AP

Interpretation Introduction

(a)

Interpretation:

The correct name for 2-hexyn-4-ol is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The correct name for 6-methoxy-1, 5-hexadiyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The correct name for 1-butyn-2-ene is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The correct name for 5-hexyne is to be stated.

Concept introduction:

The naming of organic compound is done such that the structure of the organic compound is correctly interpreted from the name.

Rules for writing IUPAC name from the structural formula are given below.

• First, identify the longest carbon chain.

• The next step is to identify the groups attached to the longest chain.

• Identify the position, location, and a number of the substituents bonded to the carbon chain.

• Use prefix di, tri, tetra if the same type of substituents are present.

• Name the substituents in alphabetical order.

Answer 14

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Answer 25

Ch. 14 - Prob. 14.1P Ch. 14 - Prob. 14.2P Ch. 14 - Prob. 14.3P Ch. 14 - Prob. 14.4P Ch. 14 - Prob. 14.5P Ch. 14 - Prob. 14.6P Ch. 14 - Prob. 14.7P Ch. 14 - Prob. 14.8P Ch. 14 - Prob. 14.9P Ch. 14 - Prob. 14.10P

Solution Summary: The author explains the correct name for 2-hexyn-4-ol and the rules for writing IUPAC name from the structural formula.

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Chapter 14 Solutions