The enols among the compounds ( A ) to ( D ) are to be identified. Also, the enols are to be converted into ketones . Concept introduction: An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.11P

Interpretation Introduction

Interpretation:

The enols among the compounds (A) to (D) are to be identified. Also, the enols are to be converted into ketones.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.11P

Interpretation Introduction

Interpretation:

The enols among the compounds (A) to (D) are to be identified. Also, the enols are to be converted into ketones.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.11P

Interpretation Introduction

Interpretation:

The enols among the compounds (A) to (D) are to be identified. Also, the enols are to be converted into ketones.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 14, Problem 14.11P

Interpretation Introduction