The NMR spectrum of CH 3 CH 2 Cl , by giving the approximate location of each NMR signal is to be sketched. Concept introduction: The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. Protons which are present in the same chemical environment that is between the same groups of atoms are known as chemically equivalent protons. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

Question

A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from the arrow. • Is the student's transformation possible? If not, check the box under the drawing area. • If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts, inorganic reagents, or other important reaction conditions above and below the arrow. • You do not need to balance the reaction, but be sure every important organic reactant or product is shown. + T G OH де OH This transformation can't be done in one step.

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Question

Chapter 14, Problem 14.16P

Interpretation Introduction

Interpretation: The NMR spectrum of CH3CH2Cl, by giving the approximate location of each NMR signal is to be sketched.

Concept introduction: The number of NMR signal in a compound is equal to the number of chemically non-equivalent protons present in that compound. Protons which are present in the same chemical environment that is between the same groups of atoms are known as chemically equivalent protons. The more the shielded proton less will be its chemical shift value and the corresponding signal will be produced at the right-hand side or lower frequency region or vice versa.

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A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from the arrow. • Is the student's transformation possible? If not, check the box under the drawing area. • If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts, inorganic reagents, or other important reaction conditions above and below the arrow. • You do not need to balance the reaction, but be sure every important organic reactant or product is shown. + T G OH де OH This transformation can't be done in one step.

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