(a) Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified. Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 1

Question

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 2

Question

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 3

Question

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Expert Solution & Answer

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Answer 4

Question

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 5

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 6

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 7

Chapter 14, Problem 14.30P

Interpretation Introduction

(a)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 8

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 9

Interpretation Introduction

(b)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 10

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 11

Interpretation Introduction

(c)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 12

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 13

Interpretation Introduction

(d)

Interpretation: The highlighted carbon atom of the given compound that absorbs farther downfield is to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around carbon, the chemical shift values of carbon varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 14 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 14 - Prob. 14.2P Ch. 14 - How many NMR signals does each compound show? a....Ch. 14 - How many 1H NMR signals does each...Ch. 14 - How many 1H NMR signals does each compound give?...Ch. 14 - Label the protons in each highlighted CH2 group as...Ch. 14 - How many 1H NMR signals would you expect for each...Ch. 14 - Prob. 14.8P Ch. 14 - For each compound, first label each different type...Ch. 14 - Label each statement as True or False. a. When a...

Solution Summary: The author illustrates how the chemical shift values of carbon varies relative to the reference signal.

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