Chemistry In Context
Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 14, Problem 14.15YT
Interpretation Introduction

Interpretation:

Using the internet as a resource and following IR spectrum functional groups should be interpreted.

  • • The five peaks appear in the given IR spectrum (Figure 14.17) and corresponding functional group should be assigned.

Concept Introduction:

IR spectroscopy: IR spectrum provides the information regarding the functional groups a compound possesses.  When a molecule is bombarded with radiation of a frequency that exactly matches the frequency of the vibration of one of its bonds, the molecules absorbs energy.

Example:

  • • In the IR spectrum, the signal just above 3000cm1 confirms the presence of  aromatic ring
  • Aromatic compound also produces a series of signals between 1450cm1 and 1650cm-1 in the IR spectrum

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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