(a) Interpretation: Whether the molecule dimethylacetylene, CH 3 − C ≡ C − CH 3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated. Concept introduction: Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Question

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Answer 1

Question

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

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Part I. Problem solving. Include all necessary calculations 13 provide plots and graphs. Complexation wl diphenyl carbazide (OPC) in acidic media is another type of sensitive photometric method used for the analysis of aqueous. hexavalent chromium. At 540nm the cherry-red complex as a result of DPC reaction w/ chromium can be photometrically measured. at this wavelength. - a 25mL The UV-vis analysis for the determination of nexavalent chromium in ground water sample is given below. The experiment was based on external calibration method w/ each measurement sample prepared are as follows lab sample analysis contained the standard 100 ppb croy cor groundwater sample, volumes used as indicated below), 12.50 mL of 0.02 M H2Soy and 5.50 ml of 100 ppm DPC (wi water to adjust final volume to 25-ml). The main stripping method was square wave voltammetry, following the conditions set in the main ASV experiment. Standard 100 Volumetric Groundwater H2SO4 0.20 M, flask Sample, mL ppb CrO4*, 100…

Answer 2

Question

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

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Answer 3

Question

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

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Answer 4

Question

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

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Answer 5

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 6

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 7

Chapter 14, Problem 14.13E

Interpretation Introduction

(a)

Interpretation:

Whether the molecule dimethylacetylene, CH3−C≡C−CH3 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule, the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the molecule sulfur hexafluoride, SF6 is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Whether the molecule phosphate ion, PO43− is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Whether the molecule glycine, (CH2)(NH2)(COOH) is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Whether the molecule cis−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 16

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 17

Interpretation Introduction

(f)

Interpretation:

Whether the molecule trans−1,2− Dichloroethylene is linear, spherical tops, prolate symmetric tops, oblate symmetric tops, or asymmetric tops is to be stated.

Concept introduction:

Nonlinear molecules can rotate in three independent and mutually perpendicular directions. It is not necessary that the rotation in one dimension is equivalent to rotations in the other two directions. The moment of inertia for each dimension of each rotation is usually different. If a molecule has three different moments of inertia, it is called an asymmetric top molecule. If a molecule has two of its three moments of inertia equal, it is called symmetric top molecule. If the two equal moments of inertia are lower than the unique moment of inertia, then the molecule is called oblate tops. If the two equal moments of inertia are higher than the unique moment of inertia, then the molecule is called prolate tops. For linear molecule the moment of inertia along the molecular axis is zero. Spherical top molecules have no net dipole moment or net dipole moment is equal to zero.

Answer 18

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Ch. 14 - Prob. 14.1E Ch. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8E Ch. 14 - Prob. 14.9E Ch. 14 - Prob. 14.10E

Solution Summary: The author explains the structure of dimethylacetylene, which is linear, spherical, or asymmetric.

Chapter 14 Solutions