EBK PHYSICAL CHEMISTRY
2nd Edition
ISBN: 8220100477560
Author: Ball
Publisher: Cengage Learning US
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Chapter 14, Problem 14.4E
What is the
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ
Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions
about this system:
?
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
0.035 atm
✓
G
00.
18
Ar
Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area.
HO-
HO-
-0
OH
OH
HO
NG
HO-
HO-
OH
OH
OH
OH
NG
OH
€
+
Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn
it into the product of the reaction.
Also, write the name of the product molecule under the drawing area.
Name: ☐
H
C=0
X
H-
OH
HO-
H
HO-
-H
CH₂OH
×
Chapter 14 Solutions
EBK PHYSICAL CHEMISTRY
Ch. 14 - Prob. 14.1ECh. 14 - Determine if the following integrals can be...Ch. 14 - What is the frequency of light having the...Ch. 14 - What is the wavelength of light having the given...Ch. 14 - What is the energy of light having each...Ch. 14 - The Cu(H2O)62+ complex has octahedral symmetry. Is...Ch. 14 - What are the wavelength, speed, and energy of a...Ch. 14 - Prob. 14.8ECh. 14 - Prob. 14.9ECh. 14 - Prob. 14.10E
Ch. 14 - Prob. 14.11ECh. 14 - Prob. 14.12ECh. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Diatomic sulfur, S2, was detected in the tail of...Ch. 14 - Prob. 14.16ECh. 14 - Prob. 14.17ECh. 14 - Prob. 14.18ECh. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Which of the following molecules should have pure...Ch. 14 - Which of the following molecules should have pure...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - The following are sets of rotational quantum...Ch. 14 - Derive equation 14.21 from the E expression...Ch. 14 - Prob. 14.28ECh. 14 - Prob. 14.29ECh. 14 - Lithium hydride, 7Li1H, is a potential fuel for...Ch. 14 - Prob. 14.31ECh. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Prob. 14.36ECh. 14 - From the data in Table 14.2, predict B for DCl D...Ch. 14 - A colleague states that the pure rotational...Ch. 14 - Prob. 14.39ECh. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Prob. 14.42ECh. 14 - Prob. 14.43ECh. 14 - Determine E for J=20J=21 for HBr assuming it acts...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Determine the number of total degrees of freedom...Ch. 14 - Prob. 14.47ECh. 14 - Prob. 14.48ECh. 14 - Prob. 14.49ECh. 14 - Prob. 14.50ECh. 14 - Prob. 14.51ECh. 14 - Prob. 14.52ECh. 14 - Prob. 14.53ECh. 14 - Prob. 14.54ECh. 14 - Prob. 14.55ECh. 14 - Prob. 14.56ECh. 14 - Prob. 14.57ECh. 14 - Prob. 14.58ECh. 14 - Prob. 14.59ECh. 14 - Prob. 14.60ECh. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Prob. 14.63ECh. 14 - Prob. 14.64ECh. 14 - Prob. 14.65ECh. 14 - Prob. 14.66ECh. 14 - Prob. 14.68ECh. 14 - Prob. 14.69ECh. 14 - Prob. 14.70ECh. 14 - Prob. 14.71ECh. 14 - Prob. 14.72ECh. 14 - Prob. 14.73ECh. 14 - Prob. 14.74ECh. 14 - Prob. 14.75ECh. 14 - Prob. 14.76ECh. 14 - Prob. 14.77ECh. 14 - Prob. 14.78ECh. 14 - Prob. 14.79ECh. 14 - Prob. 14.80ECh. 14 - Prob. 14.81ECh. 14 - Prob. 14.82ECh. 14 - Prob. 14.83ECh. 14 - Prob. 14.84ECh. 14 - Prob. 14.85ECh. 14 - Dioctyl sulfide, (C8H17)2S, and hexadecane,...Ch. 14 - Where would you expect vibrations for ethyl...Ch. 14 - Prob. 14.88ECh. 14 - Prob. 14.89ECh. 14 - Prob. 14.90ECh. 14 - Prob. 14.91ECh. 14 - Prob. 14.92ECh. 14 - Prob. 14.93ECh. 14 - Prob. 14.94ECh. 14 - The mutual exclusion rule states that for certain...Ch. 14 - Prob. 14.96ECh. 14 - Prob. 14.97ECh. 14 - Prob. 14.98ECh. 14 - Prob. 14.99ECh. 14 - Construct and compare the energy level diagrams...Ch. 14 - Prob. 14.101E
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- Draw the Haworth projection of the disaccharide made by joining D-glucose and D-mannose with a ẞ(1-4) glycosidic bond. If the disaccharide has more than one anomer, you can draw any of them. Click and drag to start drawing a structure. Xarrow_forwardEpoxides can be opened in aqueous acid or aqueous base to produce diols (molecules with two OH groups). In this question, you'll explore the mechanism of epoxide opening in aqueous acid. 2nd attempt Be sure to show all four bonds at stereocenters using hash and wedge lines. 0 0 Draw curved arrows to show how the epoxide reacts with hydronium ion. 100 +1: 1st attempt Feedback Be sure to show all four bonds at stereocenters using hash and wedge lines. See Periodic Table See Hint H A 5 F F Hr See Periodic Table See Hintarrow_forward03 Question (1 point) For the reaction below, draw both of the major organic products. Be sure to consider stereochemistry. > 1. CH₂CH₂MgBr 2. H₂O 3rd attempt Draw all four bonds at chiral centers. Draw all stereoisomers formed. Draw the structures here. e 130 AN H See Periodic Table See Hint P C Brarrow_forward
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