
(a)
Interpretation:
The number of IR-active vibrations for
Concept introduction:
The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are IR or Raman active. If a molecule has centre of symmetry, then the modes which are IR-active will be Raman inactive and the modes that are IR-inactive will be Raman active. The total number of vibrational degrees of freedom for nonlinear molecule is represented by
(b)
Interpretation:
The number of IR-active vibrations for
Concept introduction:
The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are IR or Raman active. If a molecule has centre of symmetry, then the modes which are IR-active will be Raman inactive and the modes that are IR-inactive will be Raman active. The total number of vibrational degrees of freedom for nonlinear molecule is represented by
(c)
Interpretation:
The number of IR-active vibrations for
Concept introduction:
The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are IR or Raman active. If a molecule has centre of symmetry, then the modes which are IR-active will be Raman inactive and the modes that are IR-inactive will be Raman active. The total number of vibrational degrees of freedom for nonlinear molecule is represented by
(d)
Interpretation:
The number of IR-active vibrations for
Concept introduction:
The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are IR or Raman active. If a molecule has centre of symmetry, then the modes which are IR-active will be Raman inactive and the modes that are IR-inactive will be Raman active. The total number of vibrational degrees of freedom for nonlinear molecule is represented by
(e)
Interpretation:
The number of IR-active vibrations for
Concept introduction:
The complex vibrations exhibit by the polyatomic molecule is known as normal modes of vibrations. The vibrational modes of a molecule are IR or Raman active. If a molecule has centre of symmetry, then the modes which are IR-active will be Raman inactive and the modes that are IR-inactive will be Raman active. The total number of vibrational degrees of freedom for nonlinear molecule is represented by

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Chapter 14 Solutions
EBK PHYSICAL CHEMISTRY
- How many chiral centers are there in the following molecule? HO 0 1 ○ 2 ♡ 4 'N'arrow_forwardThe following chemical structure represents a molecule of what molecular formula?arrow_forwardWhich region(s) of the following phospholipid is/are hydrophobic? RO I hydro-water phobic-dislikes = Hydrophobic dislikes water ○ I only Il only I and III only II and IV only O II, III, and IV only III || IVarrow_forward
- Given the following data, determine the order of the reaction with respect to H2. H2(g) + 21Cl(g) → I2(g) + 2HCl(g) Experiment [H2] (torr) [ICI] (torr) Rate (M/s) 1 250 325 0.266 2 250 81 0.0665 3 50 325 0.266arrow_forwardWhich one of the following molecules is chiral? H- NH₂ H3C དང་།་ OH H HO H₂N HO- -H CHO -OH H HO- OH H- -H CH₂OH OHarrow_forwardThe structure of an unsaturated phospholipid is shown below. Which region of the molecule is most hydrophilic ? H₂N-CH₂ H₂C IV CH3 CH3 hydro-water philic-likes = Hydrophilic likes water ○ IV All regions are equally hydrophilic. IIIarrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
