General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)
11th Edition
ISBN: 9780134097329
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
Question
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Chapter 14, Problem 113FP
Interpretation Introduction

(a)

Interpretation:

The approximate temperature at which the steam distillation occurs should be determined.

Concept introduction:

Boiling occurs when the total vapor pressure of two immiscible liquids equals to atmospheric pressure (1 atm). So by steam distillation, organic compounds which are insoluble in water can be extracted in low temperature without decomposition.

Interpretation Introduction

(b)

Interpretation:

Why the proportions of the two liquids condensed from the vapor is independent of the composition of the boiling mixture, as long as both liquids are present in the boiling mixture should be explained.

Concept introduction:

A liquid boils when vapor pressure of the liquid equals to external pressure. Vapor pressure of a liquid at a certain temperature depends on its enthalpy of vaporization, when the enthalpy of vaporization is low; vapor pressure of the liquid at a certain temperature is high, because it needs less energy to escape into vapor phase.

Interpretation Introduction

(c)

Interpretation:

Which of the two liquids, water or Cinnamaldehyde, condenses in the greater quantity by mass should be explained.

Concept introduction:

Boiling point depends on intermolecular forces. Higher the intermolecular forces, higher the boiling point. Hence, a liquid with higher boiling point will have a lower vapor pressure at certain temperature compared to a liquid with lower boiling point. However liquid starts to boil when the vapor pressure of the liquid equals to external pressure.

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Chapter 14 Solutions

General Chemistry: Principles And Modern Applications Plus Mastering Chemistry With Pearson Etext -- Access Card Package (11th Edition)

Ch. 14 - Prob. 11ECh. 14 - You are asked to prepare 125.0 mL of 0.0321 M...Ch. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Prob. 16ECh. 14 - The sulfate ion level in a municipal water supply...Ch. 14 - A water sample is found to have 9.4 ppb of...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - How many milliliters at the ethanol-water solution...Ch. 14 - Prob. 22ECh. 14 - What is the molarity of CO2 in liter ocean water...Ch. 14 - Prob. 24ECh. 14 - Prob. 25ECh. 14 - Prob. 26ECh. 14 - How many grams of iodine, l2 , must be dissolved...Ch. 14 - How many grams of water would you add to 1.00 kg...Ch. 14 - Prob. 29ECh. 14 - A 10.00%-by-man solution of ethanol, CH2CH2OH , in...Ch. 14 - Prob. 31ECh. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Prob. 34ECh. 14 - What volume of glycerol,...Ch. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - The amount of CO2 in the ocean is approximately...Ch. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Prob. 41ECh. 14 - Prob. 42ECh. 14 - Under an O2(g) pressure of 1.00 atm, 28.31mL of...Ch. 14 - Prob. 44ECh. 14 - Natural gas consists about 90% methane, CM. Assume...Ch. 14 - At 1.00 atm, the solubility of O2 in water is...Ch. 14 - The aqueous solubility at 20C of Ar at 1.00 atm...Ch. 14 - Prob. 48ECh. 14 - Prob. 49ECh. 14 - Prob. 50ECh. 14 - What are the partial and total vapor pressures of...Ch. 14 - Prob. 52ECh. 14 - Calculate the vapor pressure at 25C of a solution...Ch. 14 - Calculate the vapor pressure at 20C of a saturated...Ch. 14 - Styrene, used in the manufacture of polystyrene...Ch. 14 - Prob. 56ECh. 14 - A benzene-toluene solution with banz=0.300 has a...Ch. 14 - Prob. 58ECh. 14 - Prob. 59ECh. 14 - Prob. 60ECh. 14 - Prob. 61ECh. 14 - Prob. 62ECh. 14 - Prob. 63ECh. 14 - Prob. 64ECh. 14 - Prob. 65ECh. 14 - Use the concentration of an istonic solution,...Ch. 14 - Prob. 67ECh. 14 - The two solutions pictured here are separated by a...Ch. 14 - of an unknown compound reduces e freezing point of...Ch. 14 - Prob. 70ECh. 14 - Prob. 71ECh. 14 - Prob. 72ECh. 14 - A compound is 42.9% C, 2.4% H, 16.7%N, and 38.1%...Ch. 14 - Nicotinamide is a water-soluble vitamin important...Ch. 14 - Prob. 75ECh. 14 - Coniferin is glycoside (a derivative of a sugar)...Ch. 14 - Cooks often add some salt to water before boding...Ch. 14 - An important test for the purity of an organic...Ch. 14 - Prob. 79ECh. 14 - If ocean water consisted of 3.5% salt, what would...Ch. 14 - Predict the approximate freezing points of 0.10m...Ch. 14 - Calculate the van’t Hoff factors of the following...Ch. 14 - NH2(aq) conducts electric current only weakly. The...Ch. 14 - Prob. 84ECh. 14 - Prob. 85ECh. 14 - Prob. 86ECh. 14 - Prob. 87IAECh. 14 - Prob. 88IAECh. 14 - Prob. 89IAECh. 14 - Prob. 90IAECh. 14 - A solid mixture consists of 85.0% KNO2 and 15.0%...Ch. 14 - Suppose you have available 2.50 L of a solution (d...Ch. 14 - Prob. 93IAECh. 14 - Prob. 94IAECh. 14 - Prob. 95IAECh. 14 - Nitrobenzene, C6H2NO2 , and benzene, C6H8 , are...Ch. 14 - Prob. 97IAECh. 14 - Prob. 98IAECh. 14 - Prob. 99IAECh. 14 - Suppose that I 00mg of gold obtained in a...Ch. 14 - At 20C , liquid benzene has a density of...Ch. 14 - The two compounds whose structures are depicted...Ch. 14 - Prob. 103IAECh. 14 - Prob. 104IAECh. 14 - Prob. 105IAECh. 14 - We noted m Figure 14-17 that the liquid and vapor...Ch. 14 - A saturated solution prepared at 70C contains...Ch. 14 - Prob. 108IAECh. 14 - Prob. 109IAECh. 14 - Prob. 110IAECh. 14 - Prob. 111IAECh. 14 - Prob. 112IAECh. 14 - Prob. 113FPCh. 14 - The phase diagram shown is for mixtures of HCI and...Ch. 14 - The laboratory device pictured on the following...Ch. 14 - Prob. 116FPCh. 14 - Prob. 117SAECh. 14 - Briefly describe each of the following ides or...Ch. 14 - Explain the important distinctions between each...Ch. 14 - Prob. 120SAECh. 14 - Prob. 121SAECh. 14 - Prob. 122SAECh. 14 - Prob. 123SAECh. 14 - An ideal liquid solution has two volatile...Ch. 14 - Prob. 125SAECh. 14 - Prob. 126SAECh. 14 - A solution (d=1.159g/mL) is 62.0% glycerol,...Ch. 14 - Prob. 128SAECh. 14 - Prob. 129SAECh. 14 - Prob. 130SAECh. 14 - Prob. 131SAECh. 14 - Prob. 132SAECh. 14 - Prob. 133SAECh. 14 - What is the mole fractions of a monvolatile solute...Ch. 14 - What is the osmotic pressure, in bar, of 15.2L of...Ch. 14 - What is the weight percent of 23.4 g of CaF2 if...Ch. 14 - Prob. 137SAECh. 14 - Prob. 138SAE
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