(a) Interpretation: The major product formed when given cycloalkane is heated with Br 2 is to be drawn. Concept introduction: Free radicals are classified as 1 ° , 2 ° or 3 ° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals. Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane.

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Answer 1

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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#1. Retro-Electrochemical Reaction: A ring has been made, but the light is causing the molecule to un- cyclize. Undo the ring into all possible molecules. (2pts, no partial credit) hv

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I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."

Answer 2

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 3

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 4

Question

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 5

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 6

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 7

Chapter 13.6, Problem 9P

Interpretation Introduction

(a)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 8

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 9

Interpretation Introduction

(b)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 10

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 11

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 12

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 13

Interpretation Introduction

(c)

Interpretation: The major product formed when given cycloalkane is heated with Br2 is to be drawn.

Concept introduction: Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substituents increases, the stability of radical increases. This is due to the fact alkyl substituents donate their electrons to electron deficient radicals.

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author illustrates the major product formed when given cycloalkane is heated with Br_ 2.

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