(a) Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn. Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1 ° , 2 ° or 3 ° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Question

3. a. Use the MS to propose at least two possible molecular formulas. For an unknown compound: 101. 27.0 29.0 41.0 50.0 52.0 55.0 57.0 100 57.5 58.0 58.5 62.0 63.0 64.0 65.0 74.0 40 75.0 76.0 20 20 40 60 80 100 120 140 160 180 200 220 m/z 99.5 68564810898409581251883040 115.0 116.0 77404799 17417M 117.0 12.9 118.0 33.5 119.0 36 133 0 1.2 157.0 2.1 159.0 16 169.0 219 170.0 17 171.0 21.6 172.0 17 181.0 1.3 183.0 197.0 100.0 198.0 200. 784 Relative Intensity 2 2 8 ō (ppm) 6 2

Answer 1

Question

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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3. a. Use the MS to propose at least two possible molecular formulas. For an unknown compound: 101. 27.0 29.0 41.0 50.0 52.0 55.0 57.0 100 57.5 58.0 58.5 62.0 63.0 64.0 65.0 74.0 40 75.0 76.0 20 20 40 60 80 100 120 140 160 180 200 220 m/z 99.5 68564810898409581251883040 115.0 116.0 77404799 17417M 117.0 12.9 118.0 33.5 119.0 36 133 0 1.2 157.0 2.1 159.0 16 169.0 219 170.0 17 171.0 21.6 172.0 17 181.0 1.3 183.0 197.0 100.0 198.0 200. 784 Relative Intensity 2 2 8 ō (ppm) 6 2

Solve the structure and assign each of the following spectra (IR and C-NMR)

1. For an unknown compound with a molecular formula of C8H100: a. What is the DU? (show your work) b. Solve the structure and assign each of the following spectra. 8 6 2 ō (ppm) 4 2 0 200 150 100 50 ō (ppm) LOD D 4000 3000 2000 1500 1000 500 HAVENUMBERI -11

Answer 2

Question

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 3

Question

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 4

Question

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

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Answer 5

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 6

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 7

Chapter 13.2, Problem 3P

Interpretation Introduction

(a)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 12

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 13

Interpretation Introduction

(d)

Interpretation: The product formed when a chlorine atom reacts with given species is to be drawn.

Concept introduction: A free radical is an atom or ion with unpaired electrons. They are reactive intermediates formed by the homolysis of covalent bond. Free radicals are classified as 1°, 2° or 3° depending upon the number of alkyl groups attached to it. The number of alkyl substitutents increases, the stability of radical increases. Radicals undergo reactions in order to complete their octet.

Answer 14

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Answer 25

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author explains the product formed when a chlorine atom reacts with given species. Free radicals are reactive intermediates formed by the homolysis of covalent bond.

Chapter 13 Solutions