(a) Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown. Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane. Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base. The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

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Answer 1

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Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 2

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 3

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 4

Question

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

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Answer 5

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

Answer 6

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Answer 7

Chapter 13.7, Problem 12P

Interpretation Introduction

(a)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.

The reaction between bromine and alkene proceeds via the formation of cyclic bromonium intermediate. This is an anti addition.

Answer 8

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

Answer 9

Interpretation Introduction

(b)

Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.

Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.

In the presence of peroxide, alkene is oxidized to epoxide. This is known as epoxidation. This is a syn addition. The weak pi bond of alkene and weak O−O bond of peroxide are broken and two new C−O bonds are formed. Breaking of bonds and formation of bonds takes place in single step. mCPBA is meta-chloroperoxybenzoic acid.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13.1 - Prob. 1P Ch. 13.1 - Prob. 2P Ch. 13.2 - Prob. 3P Ch. 13.3 - Prob. 4P Ch. 13.3 - Prob. 5P Ch. 13.4 - Prob. 7P Ch. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9P Ch. 13.6 - Prob. 10P Ch. 13.7 - Prob. 11P

Solution Summary: The author explains the steps and reagents needed to convert cyclohexane into given compound.

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Chapter 13 Solutions