It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule. Concept Introduction: Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms. Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal). Stereoisomers: differ in their spatial arrangement of atoms.

Question

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Answer 1

Question

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

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1. Using Online resources and chemical structures hand draw four different organic compounds (not those already shown in your handout) that are chiral, optically active (a pair of enantiomers will count as one). Pay attention to correct stereochemistry 2. Write or type a short paragraph to Discuss the stereochemical relationship between the four compounds.

Answer 2

Question

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

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Answer 3

Question

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

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Answer 4

Question

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

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See solution

Answer 5

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 6

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 7

Chapter 13.4, Problem 4P

(a)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 8

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 9

(b)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 10

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 11

(c).

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 12

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 13

(d)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 14

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 15

(e)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 16

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 17

(f)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 18

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 19

(g)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 20

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 21

(h)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 22

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 23

(i)

Interpretation Introduction

Interpretation:

It should be determined that how many alkyl chlorides obtained by monochlorination of the given alkane molecule.

Concept Introduction:

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

Structural isomers: They have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).

Stereoisomers: differ in their spatial arrangement of atoms.

Answer 24

Expert Solution & Answer

Answer 25

Expert Solution & Answer

Answer 26

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Answer 27

Ch. 13.2 - Prob. 1P Ch. 13.2 - Write the steps for formation of...Ch. 13.3 - Prob. 3P Ch. 13.4 - Prob. 4P Ch. 13.5 - Prob. 7P Ch. 13.5 - a. Would chlorination or bromination produce a...Ch. 13.5 - Prob. 10P Ch. 13.6 - Prob. 11P Ch. 13.7 - Prob. 12P Ch. 13.7 - Prob. 13P

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