ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 13.13, Problem 17P
Interpretation Introduction

Interpretation:

The structural formula for the organic major product of each of the given reaction is to be written.

Concept introduction:

The regioselectivity of substitution in aromatic compounds depends on the substituent already attached to the ring.

Certain substituents are ortho and para directing while certain substituents are meta directing.

The reaction of nitric acid with sulfuric acid generates the nitronium ion, this nitronium ion is an active electrophile and reacts with the pi electron system of the benzene or aromatic ring.

Arenes, upon reacts with chlorine in presence of a Lewis acid catalyst like iron (III) chloride, undergo chlorination. One hydrogen atom attached to the arene is substituted by chlorine.

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