ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 13, Problem 56P
Interpretation Introduction

Interpretation:

A reasonable mechanism for the isomerization of 2-isopropyl-1,3,5-trimethylbenzene to 1-isopropyl-2,4,5-trimethylbenzene when heated with aluminum chloride and a trace amount of HCl for four hours at 50oC is to be suggested.

Concept Introduction:

If a reaction can proceed through different pathways, the higher energy transition state or intermediate is formed under thermodynamic control and leads to a more stable product.

Isomer with higher steric interactions is relatively less stable.

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