ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
6th Edition
ISBN: 9781260325294
Author: SMITH
Publisher: RENT MCG
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Chapter 1.3, Problem 9P
Interpretation Introduction

(a)

Interpretation: The formal charge on the O atom in the given species that contains a multiple bond to O is to be calculated.

Concept Introduction: Formal charge is the electrostatic charge an atom in a molecule or polyatomic ion if all bonding electron are shared equally between pairs of atoms. The formal charge for an atom in a molecule or ion is calculated on the basis of the Lewis structure of the molecule or ion.

Interpretation Introduction

(b)

Interpretation: The formal charge on the O atom in the given species that contains a multiple bond to O is to be calculated.

Concept Introduction: Formal charge is the electrostatic charge an atom in a molecule or polyatomic ion if all bonding electron are shared equally between pairs of atoms. The formal charge for an atom in a molecule or ion is calculated on the basis of the Lewis structure of the molecule or ion.

Interpretation Introduction

(c)

Interpretation: The formal charge on the O atom in the given species that contains a multiple bond to O is to be calculated.

Concept Introduction: Formal charge is the electrostatic charge an atom in a molecule or polyatomic ion if all bonding electron are shared equally between pairs of atoms. The formal charge for an atom in a molecule or ion is calculated on the basis of the Lewis structure of the molecule or ion.

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With reference to cation B, label each species as an isomer, a resonance structure, or neither.
Considering the structure on the far left as the original resonance structure, which of the subsequent resonance structures (A-D) is implausible.   Explain why you believe the resonance structure to be implausible.
How are the molecules or ions in each pair related? Classify them as resonance structures, isomers, or neither.

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ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS

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