ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS
6th Edition
ISBN: 9781260325294
Author: SMITH
Publisher: RENT MCG
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Chapter 1, Problem 88P
Interpretation Introduction

(a)

Interpretation: The curved arrows that show the movement of electrons in step [1] are to be added.

Concept introduction: In the representation of a chemical reaction, the movement of electrons is shown by the curved arrows. This method shows the movement of electrons of electrons in resonance structures as well.

Interpretation Introduction

(b)

Interpretation: The curved arrows that helps in the identification of structure X in the given reaction are to be drawn and the conversion of structure X into phenol and HCl is to be shown in step [3].

Concept introduction: In the representation of a chemical reaction, the movement of electrons is shown by the curved arrows. This method shows the movement of electrons of electrons in resonance structures as well.

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The curved arrow notation introduced in Section 1.6B is a powerfulmethod used by organic chemists to show the movement of electronsnot only in resonance structures, but also in chemical reactions.Because each curved arrow shows the movement of two electrons,following the curved arrows illustrates what bonds are broken andformed in a reaction. Consider the following three-step process. (a) Addcurved arrows in Step [1] to show the movement of electrons. (b) Use thecurved arrows drawn in Step [2] to identify the structure of X. X isconverted in Step [3] to phenol and HCl.
The curved arrow notation introduced in Section 1.6B is a powerful method used by organic chemists to show the movement of electrons not only in resonance structures, but also in chemical reactions.Because each curved arrow shows the movement of two electrons, following the curved arrows illustrates what bonds are broken and formed in a reaction. Consider the following three-step process. (a) Add curved arrows in Step [1] to show the movement of electrons. (b) Use the curved arrows drawn in Step [2] to identify the structure of X. X is converted in Step [3] to phenol and HCl.
Consider lisinopril, a drug used primarily in the treatment of high blood pressure, heart failure, and after heart attacks. (a) Complete the Lewis structure of lisinopril, showing all valence electrons.                 (b) Use the valence-shell electron-pair repulsion (VSEPR) model (Section 3.10) to predict all bond angles in lisinopril. (c) Which is the most polar bond in lisinopril? (d) Is lisinopril polar or nonpolar? (e) Is lisinopril expected to possess resonance (Section 3.9)? Explain why or why not. (f) Name the various functional groups in lisinopril. (g) What is the molecular formula of lisinopril? (h) What intermolecular forces are expected to exist between molecules of lisinopril in close proximity to one another (Section 5.7)?

Chapter 1 Solutions

ORGANIC CHEMISTRY W/BIOLOGICAL TOPICS

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