(a) Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated. Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

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Answer 1

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Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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A J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3

1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.

3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ

Answer 2

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Answer 3

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Answer 4

Question

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Answer 5

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

Answer 6

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Answer 7

Chapter 1, Problem 83P

Interpretation Introduction

(a)

Interpretation: The reason for difference in bond lengths of the bond [1] and bond [2] is to be stated.

Concept introduction: With an increase in the s character, bond strength increases and ultimately bond length decreases. This is because the electrons are held more tightly and closer to the nucleus by the hybrid orbitals.

Answer 8

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 1.1 - While the most common isotope of nitrogen has a...Ch. 1.2 - Label each bond in the following compounds as...Ch. 1.3 - Draw a valid Lewis structure for each species. a....Ch. 1.3 - Prob. 9P Ch. 1.4 - Draw Lewis structures for each molecular formula....Ch. 1.6 - Classify each pair of compounds as isomers or...Ch. 1.6 - Prob. 12P Ch. 1.6 - Prob. 13P Ch. 1.6 - Prob. 14P Ch. 1.6 - Prob. 16P

Solution Summary: The author explains that bond length and bond strength are determined by s character. Resonance plays a significant role in stabilizing the molecule.

Concept explainers

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Chapter 1 Solutions

Solution Summary: The author explains that bond length and bond strength are determined by s character. Resonance plays a significant role in stabilizing the molecule.

Concept explainers

(b) Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated. Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.

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Chapter 1 Solutions

(b)

Interpretation: The reason for equal bond length of bonds [3] and [4] and shorter bond length than bond [2] is to be stated.

Concept introduction: Resonance plays a significant role in stabililizing the molecule and it is responsible for properties exhibited by the molecule.