Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 13, Problem 94E
An aqueous CaCl2 solution has a vapor pressure of 81.6 mmHg at 50°C. The vapor pressure of pure water at this temperature is 92.6 mmHg. What is the concentration of CaCl2 in mass percent? (Assume complete dissociation of the solute.)
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
Chapter 13 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 13 - What is a solution? What are the solute and...Ch. 13 - What does it mean when we say that a substance is...Ch. 13 - Why do two ideal gases thoroughly mix when...Ch. 13 - Prob. 4ECh. 13 - Prob. 5ECh. 13 - Explain how the relative strengths of...Ch. 13 - What does the statement like dissolves like mean...Ch. 13 - Prob. 8ECh. 13 - What is the heat of hydration(Hhydration)? How...Ch. 13 - Prob. 10E
Ch. 13 - How does temperature affect the solubility of a...Ch. 13 - Prob. 12ECh. 13 - How does pressure affect the solubility of a gas...Ch. 13 - What is Henry’s law? For what kinds of...Ch. 13 - Prob. 15ECh. 13 - How are parts by mass and parts by volume used in...Ch. 13 - Prob. 17ECh. 13 - What is Raoult’s law? For what kind of...Ch. 13 - Explain the difference between an ideal and a...Ch. 13 - Prob. 20ECh. 13 - Prob. 21ECh. 13 - What are colligative properties?Ch. 13 - Prob. 23ECh. 13 - Explain the significance of the van’t Hoff factor...Ch. 13 - Prob. 25ECh. 13 - Pick an appropriate solvent from Table 13.3 to...Ch. 13 - Which molecule would you expect to be more soluble...Ch. 13 - Prob. 28ECh. 13 - Prob. 29ECh. 13 - Prob. 30ECh. 13 - When ammonium chloride (NH4Cl) is dissolved in...Ch. 13 - Prob. 32ECh. 13 - Prob. 33ECh. 13 - Use the given data to calculate the heats of...Ch. 13 - Lithium iodide has a lattice energy of...Ch. 13 - Prob. 36ECh. 13 - A solution contains 25 g of NaCl per 100.0 g of...Ch. 13 - A solution contains 32 g of KNO3 per 100.0 g of...Ch. 13 - Prob. 39ECh. 13 - A KCI solution containing 42 g of KCI per 100.0 g...Ch. 13 - Some laboratory procedures involving...Ch. 13 - A person preparing a fish tank fills the tank with...Ch. 13 - Prob. 43ECh. 13 - Scuba divers breathing air at increased pressure...Ch. 13 - Calculate the mass of nitrogen dissolved at room...Ch. 13 - Use Henry’s law to determine the molar solubility...Ch. 13 - An aqueous NaCl solution is made using 112 g of...Ch. 13 - Prob. 48ECh. 13 - To what volume should you dilute 50.0 mL of a...Ch. 13 - Prob. 50ECh. 13 - Silver nitrate solutions are used to plate silver...Ch. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - You can purchase nitric acid in a concentrated...Ch. 13 - You can purchase hydrochloric acid in a...Ch. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Prob. 59ECh. 13 - Prob. 60ECh. 13 - Prob. 61ECh. 13 - Prob. 62ECh. 13 - Prob. 63ECh. 13 - Prob. 64ECh. 13 - A beaker contains 100.0 mL of pure water. A second...Ch. 13 - Which solution has the highest vapor pressure? a....Ch. 13 - Calculate the vapor pressure of a solution...Ch. 13 - A solution contains naphthalene (C10H8) dissolved...Ch. 13 - A solution contains 50.0 g of heptane (C7H16) and...Ch. 13 - A solution contains a mixture of pentane and...Ch. 13 - A solution contains 4.08 g of chloroform (C3H8O3)...Ch. 13 - A solution of methanol and water has a mole...Ch. 13 - Prob. 73ECh. 13 - An ethylene glycol solution contains 21.2 g of...Ch. 13 - Calculate the freezing point and melting point of...Ch. 13 - Calculate the freezing point and melting point of...Ch. 13 - An aqueous solution containing 17.5 g of an...Ch. 13 - An aqueous solution containing 35.9 g of an...Ch. 13 - Calculate the osmotic pressure of a solution...Ch. 13 - Prob. 80ECh. 13 - A solution containing 27.55 mg of an unknown...Ch. 13 - Prob. 82ECh. 13 - Calculate the freezing point and boiling point...Ch. 13 - Calculate the freezing point and boiling point in...Ch. 13 - What mass of salt (NaCl) should you add to 1.00 L...Ch. 13 - Prob. 86ECh. 13 - Use the van’t Hoff factors in Table 13.7 to...Ch. 13 - Prob. 88ECh. 13 - A 1.2-m aqueous solution of an ionic compound with...Ch. 13 - A 0.95-m aqueous solution of an ionic compound...Ch. 13 - Prob. 91ECh. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - An aqueous CaCl2 solution has a vapor pressure of...Ch. 13 - Prob. 95ECh. 13 - Prob. 96ECh. 13 - Potassium perchlorate (KClO4) has a lattice energy...Ch. 13 - Sodium hydroxide (NaOH) has a lattice energy of...Ch. 13 - Prob. 99ECh. 13 - Prob. 100ECh. 13 - Prob. 101ECh. 13 - Water softeners often replace calcium ions in hard...Ch. 13 - Prob. 103ECh. 13 - Prob. 104ECh. 13 - Prob. 105ECh. 13 - Prob. 106ECh. 13 - An isotonic solution contains 0.90% NaCl mass to...Ch. 13 - Prob. 108ECh. 13 - Prob. 109ECh. 13 - When HNO2 dissolves in water, it partially...Ch. 13 - Prob. 111ECh. 13 - Prob. 112ECh. 13 - Prob. 113ECh. 13 - Distillation is a method of purification based on...Ch. 13 - Prob. 115ECh. 13 - Find the mass of urea (CH4N2O) needed to prepare...Ch. 13 - A solution contains 10.05 g of unknown compound...Ch. 13 - Prob. 118ECh. 13 - Prob. 119ECh. 13 - Prob. 120ECh. 13 - The small bubbles that form on the bottom of a...Ch. 13 - The vapor above a mixture of pentane and hexane at...Ch. 13 - A 1.10-g sample contains only glucose (C6H12O6)...Ch. 13 - Prob. 124ECh. 13 - Two alcohols, isopropyl alcohol and propyl...Ch. 13 - A metal, M, of atomic mass 96 amu reacts with...Ch. 13 - Prob. 127ECh. 13 - Prob. 128ECh. 13 - A solution is prepared by dissolving 11.60 g of a...Ch. 13 - Substance A is a nonpolar liquid and has only...Ch. 13 - Prob. 131ECh. 13 - Prob. 132ECh. 13 - Prob. 133ECh. 13 - Prob. 134ECh. 13 - Prob. 135ECh. 13 - Have each group member make a flashcard with one...Ch. 13 - Prob. 137ECh. 13 - Prob. 138ECh. 13 - Prob. 139ECh. 13 - Prob. 140ECh. 13 - Which compound is most soluble in octane (C8H18)?...Ch. 13 - Prob. 2SAQCh. 13 - A 500.0-mL sample of pure water is allowed to come...Ch. 13 - Prob. 4SAQCh. 13 - Prob. 5SAQCh. 13 - Prob. 6SAQCh. 13 - What is the vapor pressure of an aqueous ethylene...Ch. 13 - Prob. 8SAQCh. 13 - What mass of glucose (C6H12O6) should you dissolve...Ch. 13 - Which aqueous solution has the highest boiling...Ch. 13 - The osmotic pressure of a solution containing 22.7...Ch. 13 - The enthalpy of solution for NaOH is -44.6 kJ/mol....Ch. 13 - A 2.4-m aqueous solution of an ionic compound with...Ch. 13 - A solution is an equimolar mixture of two volatile...Ch. 13 - An aqueous solution is in equilibrium with a...
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY