ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Chapter 13, Problem 8PP
Interpretation Introduction

Interpretation:

The structures of the compounds, D, E and F are to be predicted for the given reaction scheme.

Concept introduction:

Ultraviolet-visible (UV-Vis) spectroscopy is when electromagnetic radiation is passed through a compound having multiple bonds, where some part of the energy is absorbed.

UV-Vis spectroscopy can differentiate between conjugated dienes and other unsaturated hydrocarbons or unconjugated dienes.

When an infra-red (IR) radiation is passed through a sample, the energy of the IR radiation is absorbed by the particle. Unlike UV-Vis, the electrons don’t jump to higher orbitals; instead, there is a change in the vibrational energy of the covalent bond within the molecule.

IR spectroscopy is used to find functional groups in a molecule.

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Stereochemistry: Three possible answers- diastereomers, enantiomers OH CH₂OH I -c=0 21108 1101 41745 HOR CH₂OH IL Но CH₂OH TIL a. Compounds I and III have this relationship with each other: enantiomers b. Compounds II and IV have this relationship with each other: c. Compounds I and II have this relationship with each other: d. *Draw one structure that is a stereoisomer of II, but neither a diastereomer nor an enantiomer. (more than one correct answer)
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Chapter 13 Solutions

ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT

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