Basic Chemistry
Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 13, Problem 87CP
Interpretation Introduction

Interpretation: To determine the Kspfor Mg(OH)2.

Concept introduction:

Solubility product may be defined as the product of concentration of products each raised to the power equals to their respective stoichiometric coefficient.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Chapter 13 Solutions

Basic Chemistry

Ch. 13.2 - 13.11 The following diagrams show the chemical...Ch. 13.2 - Prob. 12PPCh. 13.3 - Write the equilibrium expression for each of the...Ch. 13.3 - Prob. 14PPCh. 13.3 - Prob. 15PPCh. 13.3 - Prob. 16PPCh. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - Prob. 21PPCh. 13.3 - Identify each of the following as a homogeneous or...Ch. 13.3 - Prob. 23PPCh. 13.3 - Prob. 24PPCh. 13.3 - Prob. 25PPCh. 13.3 - What is the numerical value of Kc for the...Ch. 13.4 - Prob. 27PPCh. 13.4 - Prob. 28PPCh. 13.4 - Indicate whether each of the following equilibrium...Ch. 13.4 - Indicale whether each of the following equilibrium...Ch. 13.4 - Prob. 31PPCh. 13.4 - The numerical value of the equilibrium constant,...Ch. 13.4 - Prob. 33PPCh. 13.4 - The numerical value of the equilibrium constant,...Ch. 13.5 - In the lower atmosphere, oxygen is converted to...Ch. 13.5 - Prob. 36PPCh. 13.5 - Hydrogen chloride can be made by reacting hydrogen...Ch. 13.5 - When heated, carbon monoxide reacts with water to...Ch. 13.5 - Use the following equation for the equilibrium of...Ch. 13.5 - Use the following equation for the equilibrium of...Ch. 13.5 - Prob. 41PPCh. 13.5 - Prob. 42PPCh. 13.6 - For each of the following slightly soluble ionic...Ch. 13.6 - For each of the following slightly soluble ionic...Ch. 13.6 - Prob. 45PPCh. 13.6 - Prob. 46PPCh. 13.6 - A saturated solution of silver carbonate, Ag2CO3 ,...Ch. 13.6 - Prob. 48PPCh. 13.6 - Calculate the molar solubility, S , of CuI if it...Ch. 13.6 - Calculate the molar solubility, S , of SnS if it...Ch. 13.6 - The CO2 level in the atmosphere has increased over...Ch. 13.6 - Prob. 52PPCh. 13 - Write the equilibrium expression for each of the...Ch. 13 - Write the equilibrium expression for each of the...Ch. 13 - Prob. 55UTCCh. 13 - Would the equilibrium constant, Ke , for the...Ch. 13 - Prob. 57UTCCh. 13 - Prob. 58UTCCh. 13 - Prob. 59APPCh. 13 - Prob. 60APPCh. 13 - For each of the following reactions, indicate if...Ch. 13 - For each of the following reactions, indicate if...Ch. 13 - Consider the reaction: (13.3) 2NH3(g)N2(g)+3H2(g)...Ch. 13 - Prob. 64APPCh. 13 - Prob. 65APPCh. 13 - Prob. 66APPCh. 13 - Prob. 67APPCh. 13 - According to Le Châtelier's principle, does the...Ch. 13 - Prob. 69APPCh. 13 - Prob. 70APPCh. 13 - The numerical value of the equilibrium constant,...Ch. 13 - The numerical value of the equilibrium constant,...Ch. 13 - For each of the following slightly soluble ionic...Ch. 13 - For each of the following slightly soluble ionic...Ch. 13 - Prob. 75APPCh. 13 - Prob. 76APPCh. 13 - Prob. 77APPCh. 13 - Prob. 78APPCh. 13 - What is the molar solubility, S , of CdS if it has...Ch. 13 - Prob. 80APPCh. 13 - Prob. 81CPCh. 13 - Prob. 82CPCh. 13 - Prob. 83CPCh. 13 - Indicate how each of the following will affect the...Ch. 13 - Prob. 85CPCh. 13 - Prob. 86CPCh. 13 - Prob. 87CPCh. 13 - Prob. 88CP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY