Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 13, Problem 83CP
(a)
Interpretation Introduction
To determine:
Effect on equilibrium concentration of ammonia on adding more hydrogen.
(b)
Interpretation Introduction
To determine:
Effect on equilibrium concentration of ammonia on increasing the temperature
(c)
Interpretation Introduction
To determine:
Effect on equilibrium concentration of ammonia on increasing the volume
(d)
Interpretation Introduction
To determine:
Effect on equilibrium concentration of ammonia on decreasing the volume
(e)
Interpretation Introduction
To determine:
Effect on equilibrium concentration of ammonia on adding catalyst
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
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-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
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(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
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-1
1
2
3
2
H,PO,
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conditions is shown. Identify possible
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write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
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b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation
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Fe3+ (aq) + e
= Fe²+ (aq)
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Chapter 13 Solutions
Basic Chemistry
Ch. 13.1 - Prob. 1PPCh. 13.1 - Prob. 2PPCh. 13.1 - In the following reaction, what happens to the...Ch. 13.1 - Prob. 4PPCh. 13.1 - Prob. 5PPCh. 13.1 - Prob. 6PPCh. 13.2 - What is meant by the term reversible reaction?Ch. 13.2 - Prob. 8PPCh. 13.2 - Which of the following are at equilibrium? a. The...Ch. 13.2 - Which of the following are not at equilibrium? a....
Ch. 13.2 - 13.11 The following diagrams show the chemical...Ch. 13.2 - Prob. 12PPCh. 13.3 - Write the equilibrium expression for each of the...Ch. 13.3 - Prob. 14PPCh. 13.3 - Prob. 15PPCh. 13.3 - Prob. 16PPCh. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - What is the numerical value of Kc for the...Ch. 13.3 - Prob. 21PPCh. 13.3 - Identify each of the following as a homogeneous or...Ch. 13.3 - Prob. 23PPCh. 13.3 - Prob. 24PPCh. 13.3 - Prob. 25PPCh. 13.3 - What is the numerical value of Kc for the...Ch. 13.4 - Prob. 27PPCh. 13.4 - Prob. 28PPCh. 13.4 - Indicate whether each of the following equilibrium...Ch. 13.4 - Indicale whether each of the following equilibrium...Ch. 13.4 - Prob. 31PPCh. 13.4 - The numerical value of the equilibrium constant,...Ch. 13.4 - Prob. 33PPCh. 13.4 - The numerical value of the equilibrium constant,...Ch. 13.5 - In the lower atmosphere, oxygen is converted to...Ch. 13.5 - Prob. 36PPCh. 13.5 - Hydrogen chloride can be made by reacting hydrogen...Ch. 13.5 - When heated, carbon monoxide reacts with water to...Ch. 13.5 - Use the following equation for the equilibrium of...Ch. 13.5 - Use the following equation for the equilibrium of...Ch. 13.5 - Prob. 41PPCh. 13.5 - Prob. 42PPCh. 13.6 - For each of the following slightly soluble ionic...Ch. 13.6 - For each of the following slightly soluble ionic...Ch. 13.6 - Prob. 45PPCh. 13.6 - Prob. 46PPCh. 13.6 - A saturated solution of silver carbonate, Ag2CO3 ,...Ch. 13.6 - Prob. 48PPCh. 13.6 - Calculate the molar solubility, S , of CuI if it...Ch. 13.6 - Calculate the molar solubility, S , of SnS if it...Ch. 13.6 - The CO2 level in the atmosphere has increased over...Ch. 13.6 - Prob. 52PPCh. 13 - Write the equilibrium expression for each of the...Ch. 13 - Write the equilibrium expression for each of the...Ch. 13 - Prob. 55UTCCh. 13 - Would the equilibrium constant, Ke , for the...Ch. 13 - Prob. 57UTCCh. 13 - Prob. 58UTCCh. 13 - Prob. 59APPCh. 13 - Prob. 60APPCh. 13 - For each of the following reactions, indicate if...Ch. 13 - For each of the following reactions, indicate if...Ch. 13 - Consider the reaction: (13.3) 2NH3(g)N2(g)+3H2(g)...Ch. 13 - Prob. 64APPCh. 13 - Prob. 65APPCh. 13 - Prob. 66APPCh. 13 - Prob. 67APPCh. 13 - According to Le Châtelier's principle, does the...Ch. 13 - Prob. 69APPCh. 13 - Prob. 70APPCh. 13 - The numerical value of the equilibrium constant,...Ch. 13 - The numerical value of the equilibrium constant,...Ch. 13 - For each of the following slightly soluble ionic...Ch. 13 - For each of the following slightly soluble ionic...Ch. 13 - Prob. 75APPCh. 13 - Prob. 76APPCh. 13 - Prob. 77APPCh. 13 - Prob. 78APPCh. 13 - What is the molar solubility, S , of CdS if it has...Ch. 13 - Prob. 80APPCh. 13 - Prob. 81CPCh. 13 - Prob. 82CPCh. 13 - Prob. 83CPCh. 13 - Indicate how each of the following will affect the...Ch. 13 - Prob. 85CPCh. 13 - Prob. 86CPCh. 13 - Prob. 87CPCh. 13 - Prob. 88CP
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