Student Study Guide and Solutions Manual T/A Organic Chemistry
Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Chapter 13, Problem 45PP

(a)

Interpretation Introduction

Interpretation:

Synthesis of 2-methyl-2-pentanol from 2-propanol of the given reaction should be explained.

Concept introduction:

Elimination: Two substituents are removed from the molecule in a single step is called E2 elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides aldehyde or ketone.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

(b)

Interpretation Introduction

Interpretation:

Synthesis of 2-methyl-2-pentanol from 2-propanol of the given reaction should be explained.

Concept introduction:

Elimination: Two substituents are removed from the molecule in a single step is called E2 elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides aldehyde or ketone.

Grignard reaction: Organomagnesium halide (Grignard reagent) undergoes reaction with a ketone or aldehyde to form an alcohol

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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI Br : Н OH H wo་ཡིག་ཐrow HO 3 D ။။ဂ CI Br H, CI Br Br H₂N OMe R IN I I N S H Br ជ័យ CI CI D OH
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Student Study Guide and Solutions Manual T/A Organic Chemistry

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