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(a)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(b)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(c)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(d)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(e)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(f)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(g)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(h)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(i)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(j)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(k)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
(l)
Interpretation:
The major product for the given reaction should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
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Chapter 13 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
- Dr. Mendel asked his BIOL 260 class what their height was and what their parent's heights were. He plotted that data in the graph below to determine if height was a heritable trait. A. Is height a heritable trait? If yes, what is the heritability value? (2 pts) B. If the phenotypic variation is 30, what is the variation due to additive alleles? (2 pts) Offspring Height (Inches) 75 67.5 60 52.5 y = 0.9264x + 4.8519 55 60 65 MidParent Height (Inches) 70 75 12pt v V Paragraph B IUA > AT2 v Varrow_forwardExperiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.arrow_forwardRel. Intensity Q 1. Which one of the following is true of the compound whose mass spectrum is shown here? Explain how you decided. 100 a) It contains chlorine. b) It contains bromine. c) It contains neither chlorine nor bromine. 80- 60- 40- 20- 0.0 0.0 TT 40 80 120 160 m/z 2. Using the Table of IR Absorptions how could you distinguish between these two compounds in the IR? What absorbance would one compound have that the other compound does not? HO CIarrow_forward
- Illustrate reaction mechanisms of alkenes with water in the presence of H2SO4, detailing each step of the process. Please show steps of processing. Please do both, I will thumb up for sure #1 #3arrow_forwardDraw the following molecule: (Z)-1-chloro-1-butenearrow_forwardIdentify the molecule as having a(n) E, Z, cis, or trans configuration. CH3 H₁₂C ○ E ○ z ○ cis transarrow_forward
- Identify the molecule as having a(n) E, Z, cis, or trans configuration. H₂C- CH3 О Е ○ cis ○ transarrow_forwardThe decomposition of dinitrogen pentoxide according to the equation: 50°C 2 N2O5(g) 4 NO2(g) + O2(g) follows first-order kinetics with a rate constant of 0.0065 s-1. If the initial concentration of N2O5 is 0.275 M, determine: the final concentration of N2O5 after 180 seconds. ...arrow_forwardDon't used hand raitingarrow_forward
- CS2(g) →CS(g) + S(g) The rate law is Rate = k[CS2] where k = 1.6 × 10−6 s−¹. S What is the concentration of CS2 after 5 hours if the initial concentration is 0.25 M?arrow_forwardCS2(g) → CS(g) + S(g) The rate law is Rate = k [CS2] where k = 1.6 × 10-6 s−1. S Calculate the half-life.arrow_forwardThe following is a first order reaction where the rate constant, k, is 6.29 x 10-3 min-*** What is the half-life? C2H4 C2H2 + H2arrow_forward
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