The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined. Concept introduction: Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes , but do oxidize alkyl benzenes containing at least one benzylic hydrogen to benzoic acid. Carboxylic acids are produced upon oxidation of alkyl benzene. In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

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Answer 1

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Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

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Answer 2

Question

Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

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Answer 3

Question

Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

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Answer 4

Question

Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

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Answer 5

Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

Answer 6

Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

Answer 7

Chapter 13, Problem 41P

Interpretation Introduction

Interpretation:

The structure of compound A formed upon reaction of 6-phenylhexanoyl chloride in carbon disulfide added is to be determined.

Concept introduction:

Inorganic oxidizing agents such as chromic acid or potassium permanganate do not oxidize benzene or alkanes, but do oxidize alkyl benzenes containing at least one

benzylic hydrogen to benzoic acid.

Carboxylic acids are produced upon oxidation of alkyl benzene.

In Friedel-Crafts acylation, the acetyl group is added to aromatic ring by reaction of acyl halides with aromatic compound in the presence of aluminum chloride as a catalyst.

Answer 8

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Answer 11

Ch. 13.2 - Based on Hammonds postulate which holds that the...Ch. 13.3 - Prob. 2P Ch. 13.3 - Using : O =N+= O : as the electrophile, write a...Ch. 13.4 - Prob. 4P Ch. 13.5 - Prob. 5P Ch. 13.6 - Prob. 6P Ch. 13.6 - Write a reasonable mechanism for the formation of...Ch. 13.6 - tert-Butylbenzene can be prepared by alkylation of...Ch. 13.6 - Prob. 9P Ch. 13.7 - The reaction shown gives a single product in 88...

Solution Summary: The author explains that the structure of compound A is determined by oxidizing alkyl benzenes to benzoic acid and carboxylic acids. The acyl group is attached to the aromatic ring through an

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