The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written. Concept introduction: In Friedel-Crafts acylation, to yield aryl ketones , acyl halides are used. In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring. The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

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Answer 1

Question

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

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Answer 2

Question

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

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Answer 3

Question

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

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Answer 4

Question

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

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Answer 5

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

Answer 6

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

Answer 7

Chapter 13, Problem 39P

Interpretation Introduction

Interpretation:

The structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction that yield a cyclic ketone is to be written.

Concept introduction:

In Friedel-Crafts acylation, to yield aryl ketones, acyl halides are used.

In the intramolecular Friedel-Craft acylation, the electrophile and nucleophile present on the same molecule, resulting in the formation of a ring.

The electron releasing effect of the methoxy group attached to benzene ring makes the ring electron rich.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 13.2 - Based on Hammonds postulate which holds that the...Ch. 13.3 - Prob. 2P Ch. 13.3 - Using : O =N+= O : as the electrophile, write a...Ch. 13.4 - Prob. 4P Ch. 13.5 - Prob. 5P Ch. 13.6 - Prob. 6P Ch. 13.6 - Write a reasonable mechanism for the formation of...Ch. 13.6 - tert-Butylbenzene can be prepared by alkylation of...Ch. 13.6 - Prob. 9P Ch. 13.7 - The reaction shown gives a single product in 88...

Solution Summary: The author explains the structure for the expected product for each of the given compounds through an intramolecular Friedel-Craft acylation reaction.

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Chapter 13 Solutions