The equilibrium constant K ′ eq is to be calculated for the reaction at pH 7 .0 and 25 ° C , using the given Δ G ′ ° value. Introduction : The “standard free-energy change” for an “ oxidation-reduction reaction ” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is Δ G ′ ° = − η F Δ E ′ ° and Δ G ′ ° = − R T ln Δ K ′ eq .

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Answer 1

Question

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

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a) What are the differences between the Direct & Indirect Immunofluorescence Assays? (0.5 mark) b) What are the advantages of the Indirect Immunofluorescence Assays? (0.5 mark) c) A Super-Resolution Imaging Technique was developed in 2018 using imidazole, a His-tag ligand conjugated with a fluorophore to report the presence of a recombinant His-tag protein target, (Sci Rep, 2018, 8:5507). How does this technique improve the image quality? (2 marks)

a) What are the differences between the Direct & Indirect Immunofluorescence Assays? b) What are the advantages of the Indirect Immunofluorescence Assays? c) A Super-Resolution Imaging Technique was developed in 2018 using imidazole, a His-tag ligand conjugated with a fluorophore to report the presence of a recombinant His-tag protein target, (Sci Rep, 2018, 8:5507). How does this technique improve the image quality?

Answer 2

Question

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

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Answer 3

Question

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Expert Solution & Answer

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Answer 4

Question

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Expert Solution & Answer

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Answer 5

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 6

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 7

Chapter 13, Problem 3P

(a)

Summary Introduction

To determine: The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 8

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 9

(b)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 10

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 11

(c)

Summary Introduction

To determine:

The equilibrium constant K′eq is to be calculated for the reaction at pH 7.0 and 25°C , using the given ΔG′° value.

Introduction:

The “standard free-energy change” for an “oxidation-reduction reaction” is directly proportional to the “difference in standard reduction potentials” of “two half-cells”. The formula is ΔG′°=−ηFΔE′° and ΔG′°=−RTlnΔK′eq .

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 13 - Prob. 1P Ch. 13 - Prob. 2P Ch. 13 - Prob. 3P Ch. 13 - Prob. 4P Ch. 13 - Prob. 5P Ch. 13 - Prob. 6P Ch. 13 - Prob. 7P Ch. 13 - Prob. 8P Ch. 13 - Prob. 9P Ch. 13 - Prob. 10P

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Chapter 13 Solutions