The rotational kinetic energy of the baseball as it travels toward home plate.

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6. We used the constant volume heat capacity, Cv, when we talked about thermodynamic cycles. It acts as a proportionality constant between energy and temperature: dU = C₁dT. You can also define a heat capacity for constant pressure processes, Cp. You can think of enthalpy playing a similar role to energy, but for constant pressure processes δαρ C = (37) - Sup Ср ат P = ат Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy and Cp for an ideal gas.

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Chapter 13, Problem 24PQ

To determine

The rotational kinetic energy of the baseball as it travels toward home plate.

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6. We used the constant volume heat capacity, Cv, when we talked about thermodynamic cycles. It acts as a proportionality constant between energy and temperature: dU = C₁dT. You can also define a heat capacity for constant pressure processes, Cp. You can think of enthalpy playing a similar role to energy, but for constant pressure processes δαρ C = (37) - Sup Ср ат P = ат Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy and Cp for an ideal gas.

Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt = 41°C. Reversible melting experiments indicate that at Tm AHm=37.7 kJ mol-1. Calculate: A. The entropy of melting, ASm- B. The Gibbs free energy of melting, AGm- C. Does the membrane become more or less ordered upon melting? D. There are 32 rotatable CH2 CH2 bonds in each molecule that can rotate more freely if the membrane melts. What is the increase in multiplicity on melting a mole of bonds?

5. Heat capacity often has a temperature dependence for real molecules, particularly if you go over a large temperature range. The heat capacity for liquid n-butane can be fit to the equation Cp(T) = a + bT where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K) to its boiling point (T₁ = 270 K). A. Compute AH for heating butane from 170 K to 270 K. B. Compute AS for the same temperature range.