Indicate which of the four cases in Table 13.3 applies to each of the following reactions. If you are unable to decide from only the information given, state why. a. PCl s ( g ) +Cl 2 ( g ) → PCl 5 ( g ) b. Δ t H ° = − 87.9 kJmol − 1 NH 4 CO 2 NH 2 ( s ) → 2 NH 3 ( g ) + CO 2 ( g ) c. NH 4 CO 2 NH 2 ( s ) → 2 NH 3 ( g ) + CO 2 ( g ) NH 4 CO 2 N H 2 ( s ) → 2 NH 3 ( g ) + CO 2 ( g )
Indicate which of the four cases in Table 13.3 applies to each of the following reactions. If you are unable to decide from only the information given, state why. a. PCl s ( g ) +Cl 2 ( g ) → PCl 5 ( g ) b. Δ t H ° = − 87.9 kJmol − 1 NH 4 CO 2 NH 2 ( s ) → 2 NH 3 ( g ) + CO 2 ( g ) c. NH 4 CO 2 NH 2 ( s ) → 2 NH 3 ( g ) + CO 2 ( g ) NH 4 CO 2 N H 2 ( s ) → 2 NH 3 ( g ) + CO 2 ( g )
Solution Summary: The author explains the Gibb's equation of thermodynamic purposed a relation between S,
Indicate which of the four cases in Table 13.3 applies to each of the following reactions. If you are unable to decide from only the information given, state why.
a.
PCl
s
(
g
)
+Cl
2
(
g
)
→
PCl
5
(
g
)
b.
Δ
t
H
°
=
−
87.9
kJmol
−
1
NH
4
CO
2
NH
2
(
s
)
→
2
NH
3
(
g
)
+
CO
2
(
g
)
c.
NH
4
CO
2
NH
2
(
s
)
→
2
NH
3
(
g
)
+
CO
2
(
g
)
NH
4
CO
2
N
H
2
(
s
)
→
2
NH
3
(
g
)
+
CO
2
(
g
)
Correctly name this compound using the IUPAC naming system by sorting the
components into the correct order.
Br
IN
Ν
H
How is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.
Part VI.
(a) calculate the λ max of the compound using woodward - Fieser rules.
(b) what types of electronic transitions are present in the compound?
(c) what are the prominent peaks in the IR spectrum of the compound?
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY