FOUND.OF COLLEGE CHEMISTRY
FOUND.OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781119234555
Author: Hein
Publisher: WILEY
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Chapter 13, Problem 22RQ

(a)

Interpretation Introduction

Interpretation:

Reason for line BC to be horizontal in below graph has to be explained. Also, reason for that happens in BC interval has to be determined.

FOUND.OF COLLEGE CHEMISTRY             , Chapter 13, Problem 22RQ , additional homework tip  1

Concept Introduction:

Heat of fusion is amount of heat required to convert solid to liquid. Every substance has different heat of fusion. Heat of fusion for ice is 384 J/g. It is represented as ΔHfus.

Heat of vaporization is quantity of heat absorbed on vaporization of a liquid. Every substance has different heat of vaporization. It is represented as ΔHv.

(b)

Interpretation Introduction

Interpretation:

Phases that are present in interval BC in below graph have to be determined.

FOUND.OF COLLEGE CHEMISTRY             , Chapter 13, Problem 22RQ , additional homework tip  2

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

Reason for line DE has to be given.

FOUND.OF COLLEGE CHEMISTRY             , Chapter 13, Problem 22RQ , additional homework tip  3

Concept Introduction:

Refer to part (a).

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The phase diagram for a pure substance is shown above. Use this diagram and your knowledge about changes of phase to answer the following questions. a)  What does point V represent? What characteristics are specific to the system only at point V?. (b)   What does each point on the curve between V and W represent? (c)   Describe the changes that the system undergoes as the temperature slowly increases from X to Y to Z at 1.0 atmosphere. Note: Please briefly explain A-C. Thank you.
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6.The diagram below is an example of Liquid-Vapor(LV) Pressure (P vs Mole Fraction).Fill out the question marks with correct number of degrees of freedom. LV Pressure – Composition (LV – PZ) Phase Diagram | How to read this phase diagram: XA = 0 Xe = 1 P = Pg Xx = 1 • We can designate the fraction of A and B in the liquid be XA and Xa, while the fraction of A and B in the gas phase be ya and Yg- XB = 0 F=? Liquid Phase F=? • Z, is the composition of A: • Below the vapor curve, or the bubble curve, A is pure vapor, and Z, = VA • Above the liquid curve, or the dew curve, A is pure liquid, and Z, = Xa P P= P F=? Vapor Phase YA = 1 YA = 0 Ya = 1 ZA Ys = 0

Chapter 13 Solutions

FOUND.OF COLLEGE CHEMISTRY

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