
Concept explainers
(a)
To determine: The general type of enzyme and cofactor(s) or reactants required during dehydrogenation reactions that would result in the formation of the product.
Introduction:
The fats disintegrate into fatty acids and glycerol. The fatty acids enter Krebs’s cycle and get involved in beta-oxidation where its carbons are removed and acetyl CoA (acetyl coenzyme A) are formed. The cholesterol molecules are formed by the utilization of acetyl CoA molecules.
(b)
To determine: The general type of enzyme and cofactor(s) or reactants required in isomerization of L- and D- leucine..
Introduction:
The amino acids are the building blocks of the macromolecules proteins. There are twenty amino acids required to make proteins in all organisms. These proteins participate in the
(c)
To determine: The general type of enzyme and cofactor(s) or reactants required in interconversion of glucose and fructose.
Introduction:
The sugars are carbohydrates that include monosaccharides and disaccharides. The sugars include glucose, sucrose, fructose, maltose, and many more sugars. The sugars are interconvertible and get converted into glucose. The glucose enters glycolysis and generates cellular energy in terms of ATP (Adenosine triphosphate).
(d)
To determine: The general type of enzyme and cofactor(s) or reactants required in the phosphorylation of glycerol to glycerol-3-phosphate.
Introduction:
The digestive products of the fats are “glycerol” and “fatty acids”. The lipase acts on the fat molecules and, the fatty acid and glycerol molecules are formed. The fats are digested in the small intestine.
(e)
To determine: The general type of enzyme and cofactor(s) or reactants required for hydrolysis of a peptide bond.
Introduction:
The proteins are formed by repeated linkage of amino acids through peptide bonds. The amino acids have “carboxyl group”, “amino group” and “R group”. The two amino acids are joined by peptide bond, such that the carboxyl group of one amino acid reacts with amino group of another amino acid. This result in formation of peptide bond and water molecule is lost.
(f)
To determine: The general type of enzyme and cofactor(s) or reactants required for the dehydrogenation of glycerol.
Introduction:
The digestive products of the fats are “glycerol” and “fatty acids”. The lipase acts on the fat molecules and the fatty acid and glycerol molecules are formed. The fats are digested in the small intestine.
(g)
To determine: The general type of enzyme and cofactor(s) or reactants required for reduction of acetaldehyde.
Introduction:
The liver performs several functions important for bodily processes. The damage done to liver affects several functions of body that includes lipids, carbohydrates, and proteins metabolism.

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Chapter 13 Solutions
Lehninger Principles of Biochemistry 7E & SaplingPlus for Lehninger Principles of Biochemistry 7E (Six-Month Access)
- 1. Identify the following alkenes as E or Z NH₂ Br 2. Draw the structures based on the IUPAC names (3R,4R)-3-bromo-4-fluoro- 1-hexene (Z)-4-bromo-2-iodo-3-ethyl- 3-heptene تر 3. For the following, predict all possible elimination product(s) and circle the major product. HO H₂SO4 Heat 80 F4 OH H2SO4 Heat 어요 F5 F6 1 A DII 4 F7 F8 F9 % & 5 6 7 * ∞ 8 BAB 3 E R T Y U 9 F D G H J K O A F11 F10arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. ○ O 1. H₂O, pyridine 2. neutralizing work-up a N W X 人 Parrow_forward✓ Check the box under each molecule that has a total of five ẞ hydrogens. If none of the molecules fit this description, check the box underneath the table. tab OH CI 0 Br xx Br None of these molecules have a total of five ẞ hydrogens. esc Explanation Check caps lock shift 1 fn control 02 F2 W Q A N #3 S 80 F3 E $ t 01 205 % 5 F5 & 7 © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibility FT * 8 R T Y U כ F6 9 FIG F11 F D G H J K L C X V B < N M H option command P H + F12 commandarrow_forward
- Draw the major product of this reaction. Ignore inorganic byproducts and the carboxylic acid side product. O 1. CHзMgBr (excess) 2. H₂O ✓ W X 人arrow_forwardIf cyclopentyl acetaldehyde reacts with NaOH, state the product (formula).arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. N S S HgCl2, H2SO4 く 8 W X Parrow_forward
- tab esc く Drawing the After running various experiments, you determine that the mechanism for the following reaction occurs in a step-wise fashion. Br + OH + Using this information, draw the correct mechanism in the space below. 1 Explanation Check F2 F1 @2 Q W A os lock control option T S # 3 80 F3 Br $ 4 0105 % OH2 + Br Add/Remove step X C F5 F6 6 R E T Y 29 & 7 F D G H Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce A F7 DII F8 C Ո 8 * 9 4 F10 F C J K L C V Z X B N M H command P ge Coarrow_forwardIndicate compound A that must react with ethylbenzene to obtain 4-ethylbenzene-1-sulfonic acid. 3-bromo-4-ethylbenzene-1-sulfonic acid.arrow_forwardPart 1 of 2 Draw the structure of A, the minor E1 product of the reaction. esc I Skip Part Check H₂O, D 2 A + Click and drag to start drawing a structure. -0- F1 F2 1 2 # 3 Q A 80 F3 W E S D F4 $ 4 % 5 F5 ㅇ F6 R T Y F G X 5 & 7 + Save 2025 McGraw Hill LLC. All Rights Reserved. DII F7 F8 H * C 80 J Z X C V B N 4 F9 6arrow_forward
- File Preview The following is a total synthesis of the pheromone of the western pine beetle. Such syntheses are interesting both because of the organic chemistry, and because of the possibility of using species specific insecticides, rather than broad band insecticides. Provide the reagents for each step. There is some chemistry from our most recent chapter in this synthesis, but other steps are review from earlier chapters. (8 points) COOEt COOEt A C COOEt COOEt COOH B OH OTS CN D E See the last homework set F for assistance on this one. H+, H₂O G OH OH The last step is just nucleophilic addition reactions, taking the ketone to an acetal, intramolecularly. But it is hard to visualize the three dimensional shape as it occurs. Frontalin, pheromone of the western pine beetlearrow_forwardFor the reaction below: 1. Draw all reasonable elimination products to the right of the arrow. 2. In the box below the reaction, redraw any product you expect to be a major product. C Major Product: Check + ◎ + X ง © Cl I F2 80 F3 I σ F4 I F5 NaOH Click and drawing F6 A 2025 McGraw Hill LLC. All Rights E F7 F8 $ # % & 2 3 4 5 6 7 8 Q W E R T Y U A S D F G H Jarrow_forwardCan I please get help with this graph. If you can show exactly where it needs to pass through.arrow_forward
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