
Concept explainers
Interpretation:
The values of
Concept introduction:
A

Answer to Problem 13F.6P
The values of
Explanation of Solution
The given moment of inertia for
The value of
The given vibrational wavenumbers for
The molar mass of
The given temperature is
The value of Planck’s constant is
The value of speed of light is
The expression that is used to calculate the standard molar Gibbs energy,
Where,
In the above expression,
The expression for translational partition function,
Where,
Substitute
Thus the value of translational partition function for
The expression for rotational partition function,
Where,
The value of
Substitute the values of
Substitute the values of
Thus, the value of rotational partition function of
The vibrational degrees of freedom of
Where,
Substitute the value of
Thus, the vibrational number for
The degeneracy of electronic ground sate is
Substitute the value of
Therefore, the value of
For
Thus the value of translational partition function for
The expression for rotational partition function,
Where,
The value of
Substitute the values of
Substitute the values of
Thus, the value of rotational partition function of
The vibrational degrees of freedom of
Where,
Substitute the value of
Thus, the vibrational number for
The degeneracy of electronic ground sate is
Substitute the value of
Therefore, the value of
Want to see more full solutions like this?
Chapter 13 Solutions
Atkins' Physical Chemistry
- Synthesize 2-Ethyl-3-methyloxirane from dimethyl(propyl)sulfonium iodide using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardSynthesize 2-Hydroxy-2-phenylacetonitrile from phenylmethanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardSynthesize N-Methylcyclohexylamine from cyclohexanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forward
- Synthesize N-Methylcyclohexylamine from cyclohexanol using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forwardIf possible, please provide the formula of the compound 3,3-dimethylbut-2-enal.arrow_forwardSynthesize 1,4-dibromobenzene from acetanilide (N-phenylacetamide) using the necessary organic or inorganic reagents. Draw the structures of the compounds.arrow_forward
- Indicate the products obtained by mixing (3-oxo-3-phenylpropyl)triphenylphosphonium bromide with sodium hydride.arrow_forwardWe mix N-ethyl-2-hexanamine with excess methyl iodide and followed by heating with aqueous Ag2O. Indicate the major products obtained.arrow_forwardIndicate the products obtained by mixing acetophenone with iodine and NaOH.arrow_forward
- Indicate the products obtained by mixing 2-Propanone and ethyllithium and performing a subsequent acid hydrolysis.arrow_forwardIndicate the products obtained if (E)-2-butenal and 3-oxo-butanenitrile are mixed with sodium ethoxide in ethanol.arrow_forwardQuestion 3 (4 points), Draw a full arrow-pushing mechanism for the following reaction Please draw all structures clearly. Note that this intramolecular cyclization is analogous to the mechanism for halohydrin formation. COH Br + HBr Brarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





