(a)
Interpretation:
The synthetic form for the given set of directions for carrying out the sequence of reactions is to be written.
Concept introduction:
The synthesis form is the balanced chemical equation that can be written in word format for carrying out the sequence of reactions with specified steps. For each synthetic step, the structures for the overall reactants, the reagents added, the overall products formed, and the required reaction conditions are to be mentioned.
The steps for writing the form of synthesis for the set of directions of reaction sequences are:
Identify the reactants, reagents, and products formed in each step from the names mentioned in the set of directions given for the reaction sequences.
The structures of reactants for the given names are to be drawn on the left side of the reaction arrow (
The reagents used are to be written above the arrow, and the reaction conditions including the solvent, temperature, pH, time of reaction, etc. are to be written below the arrow. Reagents must be written in the form in which they can be added, not as they appear in the mechanism.
If more than one sequence is combined in one step, then the reagents are numbered according to their sequence, and the reagents can be written above as well as below the arrow. For the combined step, only the product of the final step is to be drawn and the intermediate products are omitted.
The structures of the products are to be drawn on the right side of reaction arrow (
The inorganic by-products and leaving groups are often irrelevant to the synthesis and are omitted.
(b)
Interpretation:
The synthetic form for the given set of directions for carrying out the sequence of reactions is to be written.
Concept introduction:
The synthesis form is the balanced chemical equation that can be written in word format for carrying out the sequence of reactions with specified steps. For each synthetic step, the structures for the overall reactants, the reagents added, the overall products formed, and the required reaction conditions are to be mentioned.
The steps for writing the form of synthesis for the set of directions of reaction sequences are:
Identify the reactants, reagents, and products formed in each step from the names mentioned in the set of directions given for the reaction sequences.
The structures of reactants for the given names are to be drawn on the left side of the reaction arrow (
The reagents used are to be written above the arrow, and the reaction conditions including solvent, temperature, pH, time of reaction, etc. are to be written below the arrow. Reagents must be written in the form in which they can be added, not as they appear in the mechanism.
If more than one sequence is combined in one step, then the reagents are numbered according to their sequence, and the reagents can be written above as well as below the arrow. For the combined step, only the product of the final step is to be drawn and the intermediate products are omitted.
The structures of the products are to be drawn on the right side of reaction arrow (
The inorganic by-products and leaving groups are often irrelevant to the synthesis and are omitted.
(c)
Interpretation:
The synthetic form for the given set of directions for carrying out the sequence of reactions is to be written.
Concept introduction:
The synthesis form is the balanced chemical equation that can be written in word format for carrying out the sequence of reactions with specified steps. For each synthetic step, the structures for the overall reactants, the reagents added, the overall products formed, and the required reaction conditions are to be mentioned.
The steps for writing the form of synthesis for the set of directions of reaction sequences are:
Identify the reactants, reagents, and products formed in each step from the names mentioned in the set of directions given for the reaction sequences.
The structures of reactants for the given names are to be drawn on the left side of the reaction arrow (
The reagents used are to be written above the arrow, and the reaction conditions including solvent, temperature, pH, time of reaction, etc. are to be written below the arrow. Reagents must be written in the form in which they can be added, not as they appear in the mechanism.
If more than one sequence is combined in one step, then the reagents are numbered according to their sequence and the reagents can be written above as well as below the arrow. For combined step, only the product of final step is to be drawn and the intermediate products are omitted.
The structures of the products are to be drawn on the right side of reaction arrow (
The inorganic by-products and leaving groups are often irrelevant to the synthesis and are omitted.
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Chapter 13 Solutions
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
- Predict the product of this organic reaction: IZ + HO i P+H₂O Specifically, in the drawing area below draw the skeletal ("line") structure of P. If there is no reasonable possibility for P, check the No answer box under the drawing area. No Answer Click and drag to start drawing a structure. ☐ :arrow_forwardPredict the products of this organic reaction: 0 O ----- A + KOH ? CH3-CH2-C-O-CH2-C-CH3 Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. X ⑤ èarrow_forwardPredict the products of this organic reaction: O CH3 + H2O + HCI A A? CH3-CH2-C-N-CH3 Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. If there's more than one product, draw them in any arrangement you like, so long as they aren't touching. If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click anywhere to draw the first atom of your structure.arrow_forward
- What is the missing reactant in this organic reaction? R+ HO-C-CH2-CH3 0= CH3 CH3 —CH, C−NH—CH CH3 + H₂O Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. Note for advanced students: you may assume no products other than those shown above are formed. No Answer Click anywhere to draw the first atom of your structure. €arrow_forward个 CHEM&131 9267 - $25 - Intro to Mail - Hutchison, Allison (Student x Aktiv Learnin https://app.aktiv.com Draw the product of the reaction shown below. Ignore inorganic byproducts. + Na2Cr2O7 Acetone, H2SO4 Type here to search Dryng OH W Prarrow_forwardPredict the products of this organic reaction: OH + NaOH A? Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click and drag to start drawing a structure. ✓ Sarrow_forward
- Predict the products of this organic reaction: CH3-C-O-CH2-CH2-C-CH3 + H₂O ? A Specifically, in the drawing area below draw the condensed structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No reaction Click anywhere to draw the first atom of your structure. :☐ darrow_forwardDE d. Draw an arrow pushing mechanism for the following IN O CI N fo 人 P Polle DELL prt sc home end ins F5 F6 F7 F8 F9 F10 F11 F12arrow_forwardPredict the products of this organic reaction: + H₂O H* ? A Specifically, in the drawing area below draw the skeletal ("line") structure of the product, or products, of this reaction. (If there's more than one product, draw them in any arrangement you like, so long as they aren't touching.) If there aren't any products because this reaction won't happen, check the No reaction box under the drawing area. No Reaction Click and drag to start drawing a structure.arrow_forward
- Predict the major organic products of the reaction below and draw them on right side of the arrow. If there will be no significant reaction, check the box below the drawing area instead. C Cl CH, OH There will be no significant reaction. + pyridine G Click and drag to start drawing a structure.arrow_forwardWhat is the missing reactant in this organic reaction? H R+ H2O Δ OH 0= CH3-CH-O-CH3 + CH3-C-OH Specifically, in the drawing area below draw the condensed structure of R. If there is more than one reasonable answer, you can draw any one of them. If there is no reasonable answer, check the No answer box under the drawing area. No Answer Click anywhere to draw the first atom of your structure. dyarrow_forwardYou are trying to determine whether the following organic reaction can be done in a single synthesis step. If so, add any missing reagents or conditions in the drawing area below. If it isn't possible to do this reaction in a single synthesis step, check the box below the drawing area instead. Note for advanced students: if you have a choice of reagents to add, you should choose the least reactive and most economical reagents possible. Cl It isn't possible to do this reaction in a single synthesis step. + T OHarrow_forward
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning