Chemistry: An Atoms-Focused Approach (Second Edition)
2nd Edition
ISBN: 9780393614053
Author: Thomas R. Gilbert, Rein V. Kirss, Stacey Lowery Bretz, Natalie Foster
Publisher: W. W. Norton & Company
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Question
Chapter 13, Problem 13.25QA
Interpretation Introduction
To find:
The difference between the average rate and instantaneous rate of a
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 13 Solutions
Chemistry: An Atoms-Focused Approach (Second Edition)
Ch. 13 - Prob. 13.1VPCh. 13 - Prob. 13.2VPCh. 13 - Prob. 13.3VPCh. 13 - Prob. 13.4VPCh. 13 - Prob. 13.5VPCh. 13 - Prob. 13.6VPCh. 13 - Prob. 13.7VPCh. 13 - Prob. 13.8VPCh. 13 - Prob. 13.9VPCh. 13 - Prob. 13.10VP
Ch. 13 - Prob. 13.11VPCh. 13 - Prob. 13.12VPCh. 13 - Prob. 13.13VPCh. 13 - Prob. 13.14VPCh. 13 - Prob. 13.15VPCh. 13 - Prob. 13.16VPCh. 13 - Prob. 13.17QACh. 13 - Prob. 13.18QACh. 13 - Prob. 13.19QACh. 13 - Prob. 13.20QACh. 13 - Prob. 13.21QACh. 13 - Prob. 13.22QACh. 13 - Prob. 13.23QACh. 13 - Prob. 13.24QACh. 13 - Prob. 13.25QACh. 13 - Prob. 13.26QACh. 13 - Prob. 13.27QACh. 13 - Prob. 13.28QACh. 13 - Prob. 13.29QACh. 13 - Prob. 13.30QACh. 13 - Prob. 13.31QACh. 13 - Prob. 13.32QACh. 13 - Prob. 13.33QACh. 13 - Prob. 13.34QACh. 13 - Prob. 13.35QACh. 13 - Prob. 13.36QACh. 13 - Prob. 13.37QACh. 13 - Prob. 13.38QACh. 13 - Prob. 13.39QACh. 13 - Prob. 13.40QACh. 13 - Prob. 13.41QACh. 13 - Prob. 13.42QACh. 13 - Prob. 13.43QACh. 13 - Prob. 13.44QACh. 13 - Prob. 13.45QACh. 13 - Prob. 13.46QACh. 13 - Prob. 13.47QACh. 13 - Prob. 13.48QACh. 13 - Prob. 13.49QACh. 13 - Prob. 13.50QACh. 13 - Prob. 13.51QACh. 13 - Prob. 13.52QACh. 13 - Prob. 13.53QACh. 13 - Prob. 13.54QACh. 13 - Prob. 13.55QACh. 13 - Prob. 13.56QACh. 13 - Prob. 13.57QACh. 13 - Prob. 13.58QACh. 13 - Prob. 13.59QACh. 13 - Prob. 13.60QACh. 13 - Prob. 13.61QACh. 13 - Prob. 13.62QACh. 13 - Prob. 13.63QACh. 13 - Prob. 13.64QACh. 13 - Prob. 13.65QACh. 13 - Prob. 13.66QACh. 13 - Prob. 13.67QACh. 13 - Prob. 13.68QACh. 13 - Prob. 13.69QACh. 13 - Prob. 13.70QACh. 13 - Prob. 13.71QACh. 13 - Prob. 13.72QACh. 13 - Prob. 13.73QACh. 13 - Prob. 13.74QACh. 13 - Prob. 13.75QACh. 13 - Prob. 13.76QACh. 13 - Prob. 13.77QACh. 13 - Prob. 13.78QACh. 13 - Prob. 13.79QACh. 13 - Prob. 13.80QACh. 13 - Prob. 13.81QACh. 13 - Prob. 13.82QACh. 13 - Prob. 13.83QACh. 13 - Prob. 13.84QACh. 13 - Prob. 13.85QACh. 13 - Prob. 13.86QACh. 13 - Prob. 13.87QACh. 13 - Prob. 13.88QACh. 13 - Prob. 13.89QACh. 13 - Prob. 13.90QACh. 13 - Prob. 13.91QACh. 13 - Prob. 13.92QACh. 13 - Prob. 13.93QACh. 13 - Prob. 13.94QACh. 13 - Prob. 13.95QACh. 13 - Prob. 13.96QACh. 13 - Prob. 13.97QACh. 13 - Prob. 13.98QACh. 13 - Prob. 13.99QACh. 13 - Prob. 13.100QACh. 13 - Prob. 13.101QACh. 13 - Prob. 13.102QACh. 13 - Prob. 13.103QACh. 13 - Prob. 13.104QACh. 13 - Prob. 13.105QACh. 13 - Prob. 13.106QACh. 13 - Prob. 13.107QACh. 13 - Prob. 13.108QACh. 13 - Prob. 13.109QACh. 13 - Prob. 13.110QACh. 13 - Prob. 13.111QACh. 13 - Prob. 13.112QACh. 13 - Prob. 13.113QACh. 13 - Prob. 13.114QACh. 13 - Prob. 13.115QACh. 13 - Prob. 13.116QACh. 13 - Prob. 13.117QACh. 13 - Prob. 13.118QACh. 13 - Prob. 13.119QACh. 13 - Prob. 13.120QACh. 13 - Prob. 13.121QACh. 13 - Prob. 13.122QACh. 13 - Prob. 13.123QACh. 13 - Prob. 13.124QACh. 13 - Prob. 13.125QACh. 13 - Prob. 13.126QACh. 13 - Prob. 13.127QACh. 13 - Prob. 13.128QACh. 13 - Prob. 13.129QACh. 13 - Prob. 13.130QACh. 13 - Prob. 13.131QACh. 13 - Prob. 13.132QACh. 13 - Prob. 13.133QACh. 13 - Prob. 13.134QACh. 13 - Prob. 13.135QACh. 13 - Prob. 13.136QACh. 13 - Prob. 13.137QACh. 13 - Prob. 13.138QACh. 13 - Prob. 13.139QACh. 13 - Prob. 13.140QACh. 13 - Prob. 13.141QACh. 13 - Prob. 13.142QACh. 13 - Prob. 13.143QA
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