Concept explainers
(a)
Interpretation:
The strongest intermolecular force between solute and solvent in the solution of hexane in octane is to be determined.
Concept introduction:
The solution is a homogenous mixture that is formed from two or more substances. It consists of two components, solute, and solvent. The substance that is present in a smaller amount and is dissolved in the other substance is called solute. The solvent is that substance which is present in a larger amount and it dissolves solute in itself.
The intermolecular forces are the forces that act between molecules, atoms or ions. They are relatively weak forces of attraction. These are of five types as hydrogen bonding, ionic bonding, ion-dipole forces, ion-induced dipole forces, van der Waals forces.
(b)
Interpretation:
The strongest intermolecular force between solute and solvent in the solution of formaldehyde in methanol is to be determined.
Concept introduction:
The solution is a homogenous mixture that is formed from two or more substances. It consists of two components, solute, and solvent. The substance that is present in a smaller amount and is dissolved in the other substance is called solute. The solvent is that substance which is present in a larger amount and it dissolves solute in itself.
The intermolecular forces are the forces that act between molecules, atoms or ions. They are relatively weak forces of attraction. These are of five types as hydrogen bonding, ionic bonding, ion-dipole forces, ion-induced dipole forces, van der Waals forces.
(c)
Interpretation:
The strongest intermolecular force between solute and solvent in the solution of bromine in carbon tetrachloride is to be determined.
Concept introduction:
The solution is a homogenous mixture that is formed from two or more substances. It consists of two components, solute, and solvent. The substance that is present in a smaller amount and is dissolved in the other substance is called solute. The solvent is that substance which is present in a larger amount and it dissolves solute in itself.
The intermolecular forces are the forces that act between molecules, atoms or ions. They are relatively weak forces of attraction. These are of five types as hydrogen bonding, ionic bonding, ion-dipole forces, ion-induced dipole forces, van der Waals forces.
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Chapter 13 Solutions
MCGRAW: CHEMISTRY THE MOLECULAR NATURE
- Nonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward
- 6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward
- 4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forward
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