MCGRAW: CHEMISTRY THE MOLECULAR NATURE
8th Edition
ISBN: 9781264330430
Author: VALUE EDITION
Publisher: MCG
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 13, Problem 13.84P
Interpretation Introduction
Interpretation:
Whether the boiling point of
Concept introduction:
The boiling point of the substance is the temperature at which the vapor pressure of the liquid becomes equal to the atmospheric pressure and the liquid changes into vapour. Liquids can change into vapors at temperatures below the boiling point through evaporation. It is the process that occurs on the liquid surface due to which it changes into vapors.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 13 Solutions
MCGRAW: CHEMISTRY THE MOLECULAR NATURE
Ch. 13.1 - State which solute is more soluble in the given...Ch. 13.1 - State which solvent can dissolve more of the given...Ch. 13.3 - Use the following data to find the combined heat...Ch. 13.3 - Prob. 13.2BFPCh. 13.4 - If air contains 78% N2 by volume, what is the...Ch. 13.4 - Prob. 13.3BFPCh. 13.5 - Prob. 13.4AFPCh. 13.5 - What is the molality of a solution made by...Ch. 13.5 - Prob. 13.5AFPCh. 13.5 - A sample of gasoline contains 1.87 g of ethanol...
Ch. 13.5 - Prob. 13.6AFPCh. 13.5 - Prob. 13.6BFPCh. 13.6 - Calculate the vapor pressure lowering of a...Ch. 13.6 - Prob. 13.7BFPCh. 13.6 - Prob. 13.8AFPCh. 13.6 - Prob. 13.8BFPCh. 13.6 - Prob. 13.9AFPCh. 13.6 - Prob. 13.9BFPCh. 13.6 - A solution is made by dissolving 31.2 g of...Ch. 13.6 - Prob. 13.10BFPCh. 13.7 - Prob. B13.1PCh. 13.7 - Prob. B13.2PCh. 13 - Prob. 13.1PCh. 13 - Prob. 13.2PCh. 13 - Prob. 13.3PCh. 13 - Which would you expect to be more effective as a...Ch. 13 - Prob. 13.5PCh. 13 - Prob. 13.6PCh. 13 - Prob. 13.7PCh. 13 - Prob. 13.8PCh. 13 - Prob. 13.9PCh. 13 - Prob. 13.10PCh. 13 - Prob. 13.11PCh. 13 - What is the strongest type of intermolecular force...Ch. 13 - Prob. 13.13PCh. 13 - Prob. 13.14PCh. 13 - Prob. 13.15PCh. 13 - Prob. 13.16PCh. 13 - Prob. 13.17PCh. 13 - Prob. 13.18PCh. 13 - Prob. 13.19PCh. 13 - Prob. 13.20PCh. 13 - Prob. 13.21PCh. 13 - Prob. 13.22PCh. 13 - Prob. 13.23PCh. 13 - What is the relationship between solvation and...Ch. 13 - Prob. 13.25PCh. 13 - Prob. 13.26PCh. 13 - Prob. 13.27PCh. 13 - Prob. 13.28PCh. 13 - Prob. 13.29PCh. 13 - Prob. 13.30PCh. 13 - Prob. 13.31PCh. 13 - Prob. 13.32PCh. 13 - Prob. 13.33PCh. 13 - Prob. 13.34PCh. 13 - Prob. 13.35PCh. 13 - Use the following data to calculate the combined...Ch. 13 - Use the following data to calculate the combined...Ch. 13 - State whether the entropy of the system increases...Ch. 13 - Prob. 13.39PCh. 13 - Prob. 13.40PCh. 13 - Prob. 13.41PCh. 13 - Prob. 13.42PCh. 13 - Prob. 13.43PCh. 13 - Prob. 13.44PCh. 13 - For a saturated aqueous solution of each of the...Ch. 13 - Prob. 13.46PCh. 13 - Prob. 13.47PCh. 13 - Prob. 13.48PCh. 13 - Prob. 13.49PCh. 13 - Prob. 13.50PCh. 13 - Prob. 13.51PCh. 13 - Prob. 13.52PCh. 13 - Prob. 13.53PCh. 13 - Prob. 13.54PCh. 13 - Prob. 13.55PCh. 13 - Calculate the molarity of each aqueous...Ch. 13 - Calculate the molarity of each aqueous...Ch. 13 - Prob. 13.58PCh. 13 - Calculate the molarity of each aqueous...Ch. 13 - How would you prepare the following aqueous...Ch. 13 - Prob. 13.61PCh. 13 - Prob. 13.62PCh. 13 - Prob. 13.63PCh. 13 - Prob. 13.64PCh. 13 - Prob. 13.65PCh. 13 - Prob. 13.66PCh. 13 - Prob. 13.67PCh. 13 - Prob. 13.68PCh. 13 - Prob. 13.69PCh. 13 - Prob. 13.70PCh. 13 - Prob. 13.71PCh. 13 - Prob. 13.72PCh. 13 - Prob. 13.73PCh. 13 - Prob. 13.74PCh. 13 - Prob. 13.75PCh. 13 - Prob. 13.76PCh. 13 - Prob. 13.77PCh. 13 - Prob. 13.78PCh. 13 - Prob. 13.79PCh. 13 - Prob. 13.80PCh. 13 - Prob. 13.81PCh. 13 - What are the most important differences between...Ch. 13 - Prob. 13.83PCh. 13 - Prob. 13.84PCh. 13 - Prob. 13.85PCh. 13 - Prob. 13.86PCh. 13 - Prob. 13.87PCh. 13 - Prob. 13.88PCh. 13 - Classify each substance as a strong electrolyte,...Ch. 13 - Prob. 13.90PCh. 13 - Prob. 13.91PCh. 13 - Which solution has the lower freezing point?
11.0...Ch. 13 - Prob. 13.93PCh. 13 - Prob. 13.94PCh. 13 - Prob. 13.95PCh. 13 - Prob. 13.96PCh. 13 - Prob. 13.97PCh. 13 - Prob. 13.98PCh. 13 - Prob. 13.99PCh. 13 - The boiling point of ethanol (C2H5OH) is 78.5°C....Ch. 13 - Prob. 13.101PCh. 13 - Prob. 13.102PCh. 13 - Prob. 13.103PCh. 13 - Prob. 13.104PCh. 13 - Prob. 13.105PCh. 13 - Prob. 13.106PCh. 13 - Prob. 13.107PCh. 13 - Prob. 13.108PCh. 13 - Prob. 13.109PCh. 13 - Prob. 13.110PCh. 13 - Prob. 13.111PCh. 13 - In a study designed to prepare new...Ch. 13 - The U.S. Food and Drug Administration lists...Ch. 13 - Prob. 13.114PCh. 13 - Prob. 13.115PCh. 13 - Prob. 13.116PCh. 13 - In a movie theater, you can see the beam of...Ch. 13 - Prob. 13.118PCh. 13 - Prob. 13.119PCh. 13 - Prob. 13.120PCh. 13 - Prob. 13.121PCh. 13 - Gold occurs in seawater at an average...Ch. 13 - Prob. 13.123PCh. 13 - Prob. 13.124PCh. 13 - Prob. 13.125PCh. 13 - Prob. 13.126PCh. 13 - Pyridine (right) is an essential portion of many...Ch. 13 - Prob. 13.128PCh. 13 - Prob. 13.129PCh. 13 - Prob. 13.130PCh. 13 - Prob. 13.131PCh. 13 - Prob. 13.132PCh. 13 - Prob. 13.133PCh. 13 - Prob. 13.134PCh. 13 - Prob. 13.135PCh. 13 - Prob. 13.136PCh. 13 - Prob. 13.137PCh. 13 - Prob. 13.138PCh. 13 - Prob. 13.139PCh. 13 - Prob. 13.140PCh. 13 - Prob. 13.141PCh. 13 - Prob. 13.142PCh. 13 - Prob. 13.143PCh. 13 - The release of volatile organic compounds into the...Ch. 13 - Although other solvents are available,...Ch. 13 - Prob. 13.146PCh. 13 - Prob. 13.147PCh. 13 - Prob. 13.148PCh. 13 - Prob. 13.149PCh. 13 - Prob. 13.150PCh. 13 - Prob. 13.151PCh. 13 - Suppose coal-fired power plants used water in...Ch. 13 - Urea is a white crystalline solid used as a...Ch. 13 - Prob. 13.154PCh. 13 - Prob. 13.155PCh. 13 - Prob. 13.156PCh. 13 - Prob. 13.157PCh. 13 - Prob. 13.158PCh. 13 - Prob. 13.159PCh. 13 - Prob. 13.160PCh. 13 - Prob. 13.161PCh. 13 - Prob. 13.162PCh. 13 - Figure 12.11 shows the phase changes of pure...Ch. 13 - KNO3, KClO3, KCl, and NaCl are recrystallized as...Ch. 13 - Prob. 13.165PCh. 13 - Prob. 13.166PCh. 13 - Prob. 13.167P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
ChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill Education
Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill Education
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY