The percent of pyridine ( C 5 H 5 N ) that leads to the formation of pyridium ion ( C 5 H 5 NH + ) in a 0.10 M aqueous solution of pyridine is to be calculated. Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution. The pH of a solution is calculated by the formula, pH = − log [ H + ] At equilibrium, the equilibrium constant expression is expressed by the formula, K b = Concentration of products Concentration of reactants The percent ionization of an acid is calculated by the formula, Percent ionization = Equilibrium concentration of [ OH − ] Initial concentration of the base × 100
The percent of pyridine ( C 5 H 5 N ) that leads to the formation of pyridium ion ( C 5 H 5 NH + ) in a 0.10 M aqueous solution of pyridine is to be calculated. Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution. The pH of a solution is calculated by the formula, pH = − log [ H + ] At equilibrium, the equilibrium constant expression is expressed by the formula, K b = Concentration of products Concentration of reactants The percent ionization of an acid is calculated by the formula, Percent ionization = Equilibrium concentration of [ OH − ] Initial concentration of the base × 100
Interpretation: The percent of pyridine
(C5H5N) that leads to the formation of pyridium ion
(C5H5NH+) in a
0.10M aqueous solution of pyridine is to be calculated.
Concept introduction: The
pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution.
The
pH of a solution is calculated by the formula,
pH=−log[H+]
At equilibrium, the equilibrium constant expression is expressed by the formula,
Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!
Chapter 13 Solutions
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