A solution prepared by mixing the given amount of bases is given. The major species present, [ OH − ] and the pH of this solution is to be calculated. Concept introduction: The pH of a solution is define as a figure that expresses the acidity of the alkalinity of a given solution. A logarithmic scale is used on which, the value 7 corresponds to a neutral species, a value less than 7 corresponds to an acid and a value greater than 7 corresponds to a base. The pH of a solution is calculated by the formula, pH = − log [ H + ] The pOH of a solution is calculated by the formula, pOH = − log [ OH − ] The sum, pH + pOH = 14 To determine: The major species present, [ OH − ] and the pH of the given solution.
A solution prepared by mixing the given amount of bases is given. The major species present, [ OH − ] and the pH of this solution is to be calculated. Concept introduction: The pH of a solution is define as a figure that expresses the acidity of the alkalinity of a given solution. A logarithmic scale is used on which, the value 7 corresponds to a neutral species, a value less than 7 corresponds to an acid and a value greater than 7 corresponds to a base. The pH of a solution is calculated by the formula, pH = − log [ H + ] The pOH of a solution is calculated by the formula, pOH = − log [ OH − ] The sum, pH + pOH = 14 To determine: The major species present, [ OH − ] and the pH of the given solution.
Solution Summary: The author explains that a solution prepared by mixing the given amount of bases is to be calculated.
Interpretation: A solution prepared by mixing the given amount of bases is given. The major species present,
[OH−] and the
pH of this solution is to be calculated.
Concept introduction: The
pH of a solution is define as a figure that expresses the acidity of the alkalinity of a given solution. A logarithmic scale is used on which, the value
7 corresponds to a neutral species, a value less than
7 corresponds to an acid and a value greater than
7 corresponds to a base.
The
pH of a solution is calculated by the formula,
pH=−log[H+]
The
pOH of a solution is calculated by the formula,
pOH=−log[OH−]
The sum,
pH+pOH=14
To determine: The major species present,
[OH−] and the
pH of the given solution.
(b)
Interpretation Introduction
Interpretation: A solution prepared by mixing the given amount of bases is given. The major species present,
[OH−] and the
pH of this solution is to be calculated.
Concept introduction: The
pH of a solution is define as a figure that expresses the acidity of the alkalinity of a given solution. A logarithmic scale is used on which, the value
7 corresponds to a neutral species, a value less than
7 corresponds to an acid and a value greater than
7 corresponds to a base.
The
pH of a solution is calculated by the formula,
pH=−log[H+]
The
pOH of a solution is calculated by the formula,
pOH=−log[OH−]
The sum,
pH+pOH=14
To determine: The major species present,
[OH−] and the
pH of the given solution.
Q4: Rank the relative nucleophilicity of halide ions in water solution and DMF solution,
respectively.
F CI
Br |
Q5: Determine which of the substrates will and will not react with NaSCH3 in an SN2 reaction to
have a reasonable yield of product.
NH2
Br
Br
Br
OH
Br
Q7: Rank the following groups in order of basicity, nucleophilicity, and leaving group ability.
a) H₂O, OH, CH3COOT
b) NH3, H₂O, H₂S
Q8: Rank the following compounds in order of increasing reactivity in a nucleophilic substitution
reaction with CN as the nucleophile.
Br
A
B
NH2
LL
F
C
D
OH
CI
LLI
E
Q9: Complete the missing entities for following reactions (e.g., major product(s), reactants,
and/or solvents) for the SN2 reactions to occur efficiently. Include curved-arrow mechanism for
reactions a) to d).
a)
H
"Cl
D
+
-OCH 3
Page 3 of 5
Chapter 13 Solutions
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