EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 9781260475685
Author: SMITH
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Textbook Question
Chapter 12C.3, Problem 10P
For each compound, first label each different type of proton and then rank
the protons in order of increasing chemical shift.
a. 
b. 
c. 
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QUESTION: For both groups of data calculate the answers attached in the image.
Give reason(s) for six from the followings [using equations if possible] a. Addition of sodium carbonate to sulfanilic acid in the Methyl Orange preparation. b. What happened if the diazotization reaction gets warmed up by mistake. c. Addition of sodium nitrite in acidified solution in MO preparation through the diazotization d. Using sodium dithionite dihydrate in the second step for Luminol preparation. e. In nitroaniline preparation, addition of the acid mixture (nitric acid and sulfuric acid) to the product of step I. f. What is the main reason of the acylation step in nitroaniline preparation g. Heating under reflux. h. Fusion of an organic compound with sodium.
HAND WRITTEN PLEASE
edict the major products of the following organic reaction:
u
A
+
?
CN
Some important notes:
• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
Explanation
Check
Click and drag to start drawing a structure.
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© 2025 McGraw Hill LLC. All Rights Reserved. Te
LMUNDARY
Chapter 12C Solutions
EBK ORGANIC CHEMISTRY
Ch. 12C.1 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 12C.1 - Prob. 2PCh. 12C.2 - How many 1H NMR signals does each...Ch. 12C.2 - How many 1H NMR signals does each compound give?...Ch. 12C.2 - Label the protons in each highlighted CH2 group as...Ch. 12C.2 - How many 1H NMR signals would you expect for each...Ch. 12C.3 - Prob. 9PCh. 12C.3 - For each compound, first label each different type...Ch. 12C.3 - Label each statement as True or False. a. When a...Ch. 12C.4 - Prob. 12P
Ch. 12C.5 - Problem 14.12 Which compound give a NMR spectrum...Ch. 12C.5 - Prob. 14PCh. 12C.6 - Prob. 15PCh. 12C.6 - For each compound give the number of 1H NMR...Ch. 12C.6 - Prob. 17PCh. 12C.7 - Prob. 18PCh. 12C.7 - Problem 14.18 Describe the NMR spectrum of each...Ch. 12C.8 - Problem 14.19 Draw a splitting diagram for in ,...Ch. 12C.8 - Problem 14.20 Identify A and B, isomers of...Ch. 12C.9 - Problem 14.21 How many signals are present in the ...Ch. 12C.9 - Problem 14.22 What protons in alcohol A give rise...Ch. 12C.9 - How many peaks are observed in the NMR signal for...Ch. 12C.10 -
Problem 14.24 Propose a structure for a compound...Ch. 12C - 14.34 (a) How many NMR signals does each of the...Ch. 12C - 14.35 (a) How many NMR signals does each compound...Ch. 12C - Prob. 38PCh. 12C - 14.37 How many NMR signals does each natural...Ch. 12C - Prob. 40PCh. 12C - 14.39 What effect does increasing the operating...Ch. 12C - Prob. 43PCh. 12C - Prob. 44PCh. 12C - Prob. 45PCh. 12C - Prob. 47PCh. 12C - Prob. 48PCh. 12C - 14.48 How many NMR signals does each compound...Ch. 12C - 14.49 Rank the highlighted carbon atoms in each...Ch. 12C - 14.50 Identify the carbon atoms that give rise to...Ch. 12C - 14.62 Reaction of with , followed by treatment...Ch. 12C - Reaction of aldehyde D with amino alcohol E in the...Ch. 12C - 14.64 Propose a structure consistent with each set...
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