Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
4th Edition
ISBN: 9781260269284
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 12.5, Problem 12.7PP
Give the IUPAC name for each compound.
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 12 Solutions
Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
Ch. 12.1 - How many hydrogen atoms are present in each...Ch. 12.1 - Which formulas represent acyclic alkanes and which...Ch. 12.2 - Are the compounds in each pair constitutional...Ch. 12.2 - Draw two isomers with molecular formula C6H14 that...Ch. 12.2 - Prob. 12.3PCh. 12.2 - Classify the carbon atoms in each compound as 1°,...Ch. 12.2 - Prob. 12.4PCh. 12.2 - Prob. 12.5PCh. 12.2 - Prob. 12.6PCh. 12.2 - Prob. 12.7P
Ch. 12.2 - Prob. 12.8PCh. 12.2 - Prob. 12.9PCh. 12.4 - Give the IUPAC name for each compound.Ch. 12.4 - Prob. 12.10PCh. 12.4 - Give the IUPAC name for each compound....Ch. 12.4 - Prob. 12.5PPCh. 12.4 - Prob. 12.6PPCh. 12.4 - Prob. 12.12PCh. 12.5 - Prob. 12.13PCh. 12.5 - Prob. 12.14PCh. 12.5 - Give the IUPAC name for each compound.Ch. 12.5 - Prob. 12.15PCh. 12.7 - Answer the following questions about pentane...Ch. 12.7 - Prob. 12.17PCh. 12.7 - Prob. 12.18PCh. 12.8 - Prob. 12.19PCh. 12.9 - Prob. 12.20PCh. 12.9 - Prob. 12.21PCh. 12.9 - Prob. 12.22PCh. 12 - Prob. 23PCh. 12 - Prob. 24PCh. 12 - The waxy coating on the surface of apple skins...Ch. 12 - Prob. 26PCh. 12 - Classify each carbon as 1°, 2°, 3°, or 4°. a....Ch. 12 - Give the structure of an alkane that fits each...Ch. 12 - Prob. 29PCh. 12 - Label each pair of compounds as constitutional...Ch. 12 - Consider compounds A, B, and C. Label each pair of...Ch. 12 - Consider compounds D,E, and F. Label each pair of...Ch. 12 - Prob. 33PCh. 12 - Consider compounds A-E and label each pair of...Ch. 12 - Draw structures that fit the following...Ch. 12 - Draw the five constitutional isomers having...Ch. 12 - Prob. 37PCh. 12 - Prob. 38PCh. 12 - Draw the five constitutional isomers that have...Ch. 12 - Pristane is a high molecular weight alkane found...Ch. 12 - Give the IUPAC name for each of the five...Ch. 12 - Give the IUPAC name for each of the five cyclic...Ch. 12 - Give the IUPAC name for each compoundCh. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each compound. c....Ch. 12 - Give the IUPAC name for each compound.Ch. 12 - Give the IUPAC name for each cycloalkane.Ch. 12 - Give the IUPAC name for each ccycloalkane.Ch. 12 - Prob. 49PCh. 12 - Give the structure corresponding to each IUPAC...Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Each of the following IUPAC names is incorrect....Ch. 12 - Draw three constitutional isomers having molecular...Ch. 12 - Draw four constitutional isomers having molecular...Ch. 12 - Draw a skeletal structure for each compound octane...Ch. 12 - Convert each compound to a skeletal structure CH3(...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Convert each skeletal structure to a complete...Ch. 12 - Which compound in each pair has the higher melting...Ch. 12 - Which compound in each pair has the higher boiling...Ch. 12 - Branching in an alkane chain decreases surface...Ch. 12 - Explain why the boiling points of heptane [CH3( CH...Ch. 12 - Explain why hexane is more soluble in...Ch. 12 - Mineral oil and Vaseline are both mixtures of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the combustion of...Ch. 12 - Write a balanced equation for the incomplete...Ch. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - Prob. 70PCh. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - A major component of animal fat is tristearin, (a)...Ch. 12 - Answer the following questions about the alkane...Ch. 12 - Prob. 82PCh. 12 - Answer the questions in Problem 12.81 for the...Ch. 12 - Prob. 84PCh. 12 - Prob. 85CPCh. 12 - Draw the structure of the 12 constitutional...Ch. 12 - Cyclopentane has a higher boiling point than...Ch. 12 - Prob. 88CP
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