(a) Interpretation: The given reaction of addition of Br 2 to an alkene should be completed. Concept Introduction: Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Question

(28 pts.) 7. Propose a synthesis for each of the following transformations. You must include the reagents and product(s) for each step to receive full credit. The number of steps is provided. (OC 4) 4 steps 4 steps OH b.

Answer 1

Question

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

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(28 pts.) 7. Propose a synthesis for each of the following transformations. You must include the reagents and product(s) for each step to receive full credit. The number of steps is provided. (OC 4) 4 steps 4 steps OH b.

LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

For the compound: C8H17NO2 Use the following information to come up with a plausible structure: 8 This compound has "carboxylic acid amide" and ether functional groups. The peaks at 1.2ppm are two signals that are overlapping one another. One of the two signals is a doublet that represents 6 hydrogens; the other signal is a quartet that represents 3 hydrogens.

Answer 2

Question

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

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Answer 3

Question

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Expert Solution & Answer

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Answer 4

Question

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Expert Solution & Answer

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Answer 5

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Answer 6

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Answer 7

Chapter 12.5, Problem 12.10QC

Interpretation Introduction

(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Answer 10

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Answer 11

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Ch. 12.3 - Prob. 12.1QC Ch. 12.3 - Prob. 12.2QC Ch. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6QC Ch. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8QC Ch. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10QC

(a) Interpretation: The given reaction of addition of Br 2 to an alkene should be completed. Concept Introduction: Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Solution Summary: The author explains that the reaction of addition of Br 2 to an alkene should be completed.

Concept explainers

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(a)

Interpretation:

The given reaction of addition of Br₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

(b)

Interpretation:

The given reaction of addition of Cl₂ to an alkene should be completed.

Concept Introduction:

Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Chapter 12 Solutions

(a) Interpretation: The given reaction of addition of Br 2 to an alkene should be completed. Concept Introduction: Chlorine and bromine react with alkenes at room temperature by addition of halogen atoms to the carbon atoms of the double bond.

Solution Summary: The author explains that the reaction of addition of Br 2 to an alkene should be completed.

Concept explainers

Videos