ORGANIC CHEMISTRY-PRINT MULTI TERM
ORGANIC CHEMISTRY-PRINT MULTI TERM
4th Edition
ISBN: 9781119832614
Author: Klein
Publisher: WILEY
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Chapter 12.13, Problem 26CC

(a)

Interpretation Introduction

Interpretation: The reagents that will aid in the transformation of the following compound is to be determined.

  ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 12.13, Problem 26CC , additional homework tip  1

Concept introduction: The final product contains two more carbon atoms than the starting material. This can be achieved by using a Grignard reagent to add the ethyl fragment. The compound will then be oxidized using a suitable oxidizing reagent to yield the desired product.

(b)

Interpretation Introduction

Interpretation: The reagents required for the transformation of the following compound are to be determined.

  ORGANIC CHEMISTRY-PRINT MULTI TERM, Chapter 12.13, Problem 26CC , additional homework tip  2

Concept introduction: The final product has one more carbon atom than the starting material. By using a suitable Grignard reagent, a substituted alcohol is formed. This alcohol can be oxidized using a suitable oxidizing agent to yield the desired ketone product.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11
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