Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
3rd Edition
ISBN: 9780321806383
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 12, Problem 93E
Interpretation Introduction
To determine: Van’t Hoff factor
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Write the complete common (not IUPAC) name of each molecule below.
Note: if a molecule is one of a pair of enantiomers, be sure you start its name with D- or L- so we know which enantiomer it is.
molecule
Ο
C=O
common name
(not the IUPAC
name)
H
☐
H3N
CH₂OH
0-
C=O
H
NH3
CH₂SH
H3N
☐
☐
X
G
(Part A) Provide structures of the FGI products and missing reagents (dashed box)
1 eq Na* H*
H
-H
B1
B4
R1
H2 (gas)
Lindlar's
catalyst
A1
Br2
MeOH
H2 (gas)
Lindlar's
catalyst
MeO.
OMe
C6H1402
B2
B3
A1
Product carbons' origins
Draw a box around product
C's that came from A1.
Draw a dashed box around
product C's that came from B1.
Classify each of the amino acids below.
Note for advanced students: none of these amino acids are found in normal proteins.
X
CH2
H3N-CH-COOH3N-CH-COO-
H3N-CH-COO
CH2
CH3-C-CH3
CH2
NH3
N
NH
(Choose one) ▼
(Choose one)
S
CH2
OH
(Choose one) ▼
+
H3N-CH-COO¯
CH2
H3N CH COO H3N-CH-COO
CH2
오오
CH
CH3
CH2
+
O
C
CH3
O=
O_
(Choose one)
(Choose one) ▼
(Choose one)
G
Chapter 12 Solutions
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
Ch. 12 - Prob. 1SAQCh. 12 - Prob. 2SAQCh. 12 - Q3. A 500.0-mL sample of pure water is allowed to...Ch. 12 - Q4. A potassium bromide solution is 7.55 %...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 11SAQCh. 12 - Q12. The enthalpy of solution for NaOH is –44.46...Ch. 12 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 12 - Q14. A solution is an equimolar mixture of two...Ch. 12 - Prob. 15SAQCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - 22. Explain why the lower vapor pressure for a...Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 12 - 31. Which molecule would you expect to be more...Ch. 12 - 32. Which molecule would you expect to be more...Ch. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 12 - 36. When lithium iodide (LiI) is dissolved in...Ch. 12 - Silver nitrate has a lattice energy of 820 kJ/mol...Ch. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - 55. Silver nitrate solutions are often used to...Ch. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - 71. Calculate the vapor pressure of a solution...Ch. 12 - Prob. 72ECh. 12 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 12 - Prob. 74ECh. 12 - 75. A solution contains 4.08 g of chloroform...Ch. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - 79. Calculate the freezing point and boiling point...Ch. 12 - 80. Calculate the freezing point and boiling...Ch. 12 - 81. An aqueous solution containing 17.5 g of an...Ch. 12 - Prob. 82ECh. 12 - 83. Calculate the osmotic pressure of a solution...Ch. 12 - Prob. 84ECh. 12 - 85. A solution containing 27.55 mg of an unknown...Ch. 12 - Prob. 86ECh. 12 - 87. Calculate the freezing point and boiling point...Ch. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - 95. A 0.100 M ionic solution has an osmotic...Ch. 12 - Prob. 96ECh. 12 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - 100. The solubility of phenol in water at 25 °C is...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - 108. The vapor above an aqueous solution contains...Ch. 12 - Prob. 109ECh. 12 - Prob. 110ECh. 12 - Prob. 111ECh. 12 - Prob. 112ECh. 12 - Prob. 113ECh. 12 - Prob. 114ECh. 12 - Prob. 115ECh. 12 - Prob. 116ECh. 12 - Prob. 117ECh. 12 - Prob. 118ECh. 12 - Prob. 119ECh. 12 - Prob. 120ECh. 12 - Prob. 121ECh. 12 - Prob. 122ECh. 12 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 12 - Prob. 124ECh. 12 - Prob. 125ECh. 12 - Prob. 126ECh. 12 - 127. A 1.10-g sample contains only glucose...Ch. 12 - 128. A solution is prepared by mixing 631 mL of...Ch. 12 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 12 - Prob. 130ECh. 12 - Prob. 131ECh. 12 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 12 - Prob. 133ECh. 12 - Prob. 134ECh. 12 - Prob. 135ECh. 12 - Prob. 136ECh. 12 - 137. If each substance listed here costs the same...Ch. 12 - Prob. 138E
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- Another standard reference electrode is the standard calomel electrode: Hg2Cl2(s) (calomel) + 2e2 Hg() +2 Cl(aq) This electrode is usually constructed with saturated KCI to keep the Cl- concentration constant (similar to what we discussed with the Ag-AgCl electrode). Under these conditions the potential of this half-cell is 0.241 V. A measurement was taken by dipping a Cu wire and a saturated calomel electrode into a CuSO4 solution: saturated calomel electrode potentiometer copper wire CuSO4 a) Write the half reaction for the Cu electrode. b) Write the Nernst equation for the Cu electrode, which will include [Cu2+] c) If the voltage on the potentiometer reads 0.068 V, solve for [Cu²+].arrow_forward2. (Part B). Identify a sequence of FGI that prepares the Synthesis Target 2,4-dimethoxy- pentane. All carbons in the Synthesis Target must start as carbons in either ethyne, propyne or methanol. Hint: use your analysis of Product carbons' origins (Part A) to identify possible structure(s) of a precursor that can be converted to the Synthesis Target using one FGI. All carbons in the Synthesis Target must start as carbons in one of the three compounds below. H = -H H = -Me ethyne propyne Synthesis Target 2,4-dimethoxypentane MeOH methanol OMe OMe MeO. OMe C₂H₁₂O₂ Product carbons' origins Draw a box around product C's that came from A1. Draw a dashed box around product C's that came from B1.arrow_forwardDraw the skeletal ("line") structure of the smallest organic molecule that produces potassium 3-hydroxypropanoate when reacted with KOH. Click and drag to start drawing a structure. Sarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY